Coordination chemistry of the bis(trifluoromethylsulfonyl)imide anion: molecular interactions in room temperature ionic liquids

被引：110
|
作者：
Williams, DB
Stoll, ME
Scott, BL
Costa, DA
Oldham, WJ
机构：
[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA
[2] Los Alamos Natl Lab, Nucl Mat Technol Div NMT15, Los Alamos, NM 87545 USA
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 11期
关键词：
D O I：
10.1039/b416830e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Room temperature ionic liquids composed of bis( trifluoromethylsulfonyl) imide anions and 1,3-ethylmethylimidazolium (EMI) cations are shown to stabilize monomeric ligand deficient transition metal complexes via four distinct binding modes: monodentate nitrogen or oxygen coordination and/or bidentate oxygen - oxygen' or nitrogen - oxygen coordination (eta(1) - N, eta(1) - O, eta(2) - O, O' and eta(2) - N,O).
引用
收藏
页码：1438 / 1440
页数：3
相关论文
共 50 条
  • [31] Molecular Structure and Interactions in the Ionic Liquid 1-Ethyl-3-methylimidazolium Bis(Trifluoromethylsulfonyl)imide
    Dhumal, Nilesh R.
    Noack, Kristina
    Kiefer, Johannes
    Kim, Hyung J.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 118 (13): : 2547 - 2557
  • [32] Electrochemistry and Mass Transport of Ytterbium(III) in Bis(trifluoromethylsulfonyl)imide-Based Room-Temperature Ionic Liquids: Effects of Temperature, Viscosity, and Electrode Materials
    Hamilton, Heather
    Hussey, Charles L.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2023, 170 (04)
  • [33] The Temperature Effect on the Transport Properties of 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquids
    E. P. Grishina
    N. O. Kudryakova
    L. M. Ramenskaya
    Yu. A. Fadeeva
    Russian Journal of Physical Chemistry A, 2018, 92 : 724 - 729
  • [34] Ionic liquids and potassium permanganate: Characterization and initial study of trioctylmethylammonium bis(trifluoromethylsulfonyl) imide
    Armstrong, Emily J.
    Harris, Clifford E.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [35] Surface tensions of binary mixtures of ionic liquids with bis(trifluoromethylsulfonyl)imide as the common anion (vol 64, pg 22, 2013)
    Oliveira, M. B.
    Dominguez-Perez, M.
    Cabeza, O.
    Lopes-da-Silva, J. A.
    Freire, M. G.
    Coutinho, J. A. P.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2014, 78 : 284 - 284
  • [36] Influence of the Cation on the Solubility of CO2 and H2 in Ionic Liquids Based on the Bis(trifluoromethylsulfonyl)imide Anion
    Johan Jacquemin
    Pascale Husson
    Vladimir Majer
    Margarida F. Costa Gomes
    Journal of Solution Chemistry, 2007, 36 : 967 - 979
  • [37] Application of aprotic ionic liquids based on bis(trifluoromethylsulfonyl) imide anion as polymer gel electrolytes for cobalt oxide symmetric supercapacitors
    Marzouki, Moomen
    Zarrougui, Ramzi
    Ghodbane, Ouassim
    JOURNAL OF ENERGY STORAGE, 2021, 40
  • [38] Influence of the cation on the solubility of CO2 and H2 in ionic liquids based on the bis(trifluoromethylsulfonyl)imide anion
    Jacquemin, Johan
    Husson, Pascale
    Majer, Vladimir
    Gomes, Margarida F. Costa
    JOURNAL OF SOLUTION CHEMISTRY, 2007, 36 (08) : 967 - 979
  • [39] Comparative study of atmospheric ionic liquids based on bis (trifluoromethylsulfonyl)imide anion and alkyl substituted cations of ammonium, pyrrolidinium and imidazolium
    Ramenskaya, L. M.
    Grishina, E. P.
    Kudryakova, N. O.
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 312 (312)
  • [40] Room temperature molten salts based on trialkylsulfonium cations and bis(trifluoromethylsulfonyl)imide
    Matsumoto, H
    Matsuda, T
    Miyazaki, Y
    CHEMISTRY LETTERS, 2000, (12) : 1430 - 1431
12345