Coordination chemistry of the bis(trifluoromethylsulfonyl)imide anion: molecular interactions in room temperature ionic liquids

被引：110
|
作者：
Williams, DB
Stoll, ME
Scott, BL
Costa, DA
Oldham, WJ
机构：
[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA
[2] Los Alamos Natl Lab, Nucl Mat Technol Div NMT15, Los Alamos, NM 87545 USA
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 11期
关键词：
D O I：
10.1039/b416830e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Room temperature ionic liquids composed of bis( trifluoromethylsulfonyl) imide anions and 1,3-ethylmethylimidazolium (EMI) cations are shown to stabilize monomeric ligand deficient transition metal complexes via four distinct binding modes: monodentate nitrogen or oxygen coordination and/or bidentate oxygen - oxygen' or nitrogen - oxygen coordination (eta(1) - N, eta(1) - O, eta(2) - O, O' and eta(2) - N,O).
引用
收藏
页码：1438 / 1440
页数：3
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