Electrochemical influence of tridentate polypyrazolylborate ligands:: Syntheses and electrochemistry of bis(η3-polypyrazolylborato)ruthenium(II) complexes

被引：14

作者：

Onishi, M

Kumagae, S

Asai, K

Kawano, H

Shigemitsu, Y

机构：

[1] Nagasaki Univ, Dept Appl Chem, Fac Engn, Nagasaki 8528521, Japan

[2] Nagasaki Univ, Grad Sch Sci & Technol, Nagasaki 8528521, Japan

[3] Ind Technol Ctr Nagasaki, Nagasaki 8560026, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 02期

关键词：

D O I：

10.1246/cl.2001.96

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Concerning electrochemically reversible [Ru(III)]/[Ru(II)] redox couples of the substituted bis(eta (3)-polypyrazolylborato)-ruthenium(II) complexes [Ru(L-1)(L-2)], two polypyrazolylborate ligands, L-1 and L-2, were independently exerted on the oxidation half-wave potentials (E-1/2) of the couples. Relative contributions DeltaE(L) of the respective polypyrazolylborates to the E-1/2 values were evaluated.

引用

页码：96 / 97

页数：2

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