Synthesis of eco-friendly ionic liquids by microwave irradiation and their applications in Michael addition

被引：0
|
作者：
Zhao Dishun [1 ]
Bao Xiaolei [1 ]
机构：
[1] Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang, Peoples R China
来源：
2009 3RD INTERNATIONAL CONFERENCE ON BIOINFORMATICS AND BIOMEDICAL ENGINEERING, VOLS 1-11 | 2009年
关键词：
ionic liquids; caprolactam; quaternary ammonium salts; microwave irradiation; Michael addition; nano-KF/Al2O3; DIELS-ALDER REACTIONS;
D O I：
暂无
中图分类号：
R318 [生物医学工程];
学科分类号：
0831 ;
摘要：
A mild, efficient and eco-friendly procedure for the synthesis of novel ionic liquids (ILs) with formula (C4H9)(4)NX-nC(6)H(11)NO (X=Cl-, Br- and Ac-, n=2-3) under microwave irradiation and solventless conditions has been investigated. The materials have been characterized by IR, H-1 NMR methods. The properties of this kind of ILs have been researched including the melting point, the viscosity, the solubility, the pH value and the conductivity. Further, these ILs have been exploited for the synthesis of Michael addition using nano-KF/Al2O3 as catalyze in short duration of time with quantitative yields, for the first time.
引用
收藏
页码：3267 / 3270
页数：4
相关论文
共 50 条
  • [21] Eco-Friendly Supercapacitors Based on Biodegradable Poly(3-Hydroxy-Butyrate) and Ionic Liquids
    Migliorini, Lorenzo
    Santaniello, Tommaso
    Borghi, Francesca
    Saettone, Paolo
    Franchini, Mauro Comes
    Generali, Gianluca
    Milani, Paolo
    NANOMATERIALS, 2020, 10 (10) : 1 - 15
  • [22] Organic reactions in ionic liquids:: MgO as efficient and reusable catalyst for the Michael addition of sulfonamides to α,β-unsaturated esters under microwave irradiation
    Zare, Abdolkarim
    Hasaninejad, Alireza
    Khalafi-Nezhad, Ali
    Zare, Ahmad R. Moosavi
    Parhami, Abolfath
    ARKIVOC, 2007, : 105 - 115
  • [23] Molten Tetrabutylammonium Bromide as Eco-Friendly Media for the Synthesis of Optically Active and Thermal Stable Polyamides under Microwave Irradiation
    Mallakpour, Shadpour
    Taghavi, Mehdi
    POLYMER JOURNAL, 2008, 40 (11) : 1049 - 1059
  • [24] Molten Tetrabutylammonium Bromide as Eco-Friendly Media for the Synthesis of Optically Active and Thermal Stable Polyamides under Microwave Irradiation
    Shadpour Mallakpour
    Mehdi Taghavi
    Polymer Journal, 2008, 40 : 1049 - 1059
  • [25] Efficient and eco-friendly process for the synthesis of bis(1H-indol-3-yl)methanes using ionic liquids
    Yadav, JS
    Reddy, BVS
    Sunitha, S
    ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (03) : 349 - 352
  • [26] Microwave-assisted synthesis using ionic liquids
    Martinez-Palou, Rafael
    MOLECULAR DIVERSITY, 2010, 14 (01) : 3 - 25
  • [27] Eco-friendly choline acetate/propionate ionic liquids as novel green electrolytes for high performance supercapacitors
    Zainul, Rahadian
    Basem, Ali
    Altayeh, Aiham O.
    Chandra, Subhash
    Brito, Nestor Augusto Estrada
    Jabbar, Abdullah Hasan
    Naranjo, Santiago Israel Logrono
    Shakir, Maha Noori
    Elawady, Ahmed
    IONICS, 2024, 30 (06) : 3617 - 3625
  • [28] Eco-Friendly Synthesis of 2,3-Disubstituted Thiazolidine-4-One Derivatives Via A Multicomponent Reaction with Microwave Irradiation in a Chiral Ionic Liquid Medium
    Hizliates, Cevher Gundogdu
    Oncuoglu, Serkan
    CHEMISTRYSELECT, 2025, 10 (03):
  • [29] A review of the application of ionic liquids as eco-friendly corrosion inhibitors for steel, aluminum, copper and magnesium alloys
    Ikeuba A.I.
    Essiet N.
    Echem O.C.
    Ezenobi N.
    Okon E.
    Okafor P.C.
    Journal of Ionic Liquids, 2024, 4 (01):
  • [30] Eco-Friendly Methodology for the Formation of Aromatic Carbon-Heteroatom Bonds by Using Green Ionic Liquids
    Richards, Kenza
    Petit, Eddy
    Legrand, Yves-Marie
    Grison, Claude
    CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (02) : 809 - 814
12345