Soft X-ray emission and high-resolution photoemission study of quasi-two-dimensional superconductor NaxHfNCl

被引:6
作者
Takeuchi, T
Tsuda, S
Yokoya, T
Tsukamoto, T
Shin, S
Hirai, A
Shamoto, S
Kajitani, T
机构
[1] RIKEN, SPRING8, Soft Xray Spect Lab, Mikazuki, Hyogo 6795148, Japan
[2] Sci Univ Tokyo, Dept Appl Phys, Shinjuku Ku, Tokyo 1628601, Japan
[3] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[4] Tohoku Univ, Dept Appl Phys, Sendai, Miyagi 9808579, Japan
来源
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS | 2003年 / 392卷
关键词
photoemission; soft X-ray emission; electronic structure; layered nitride chloride superconductor;
D O I
10.1016/S0921-4534(03)00752-4
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have performed soft X-ray emission (SXE) and high-resolution photoemission (PE) spectroscopy to study the electronic structures of beta-HfNCl and Na-intercalated HfNCl. Both the PE and SXE spectra of Na0.37HfNCl show an additional structure within the band gap of beta-HfNCl, without an apparent shift in the energy position of valence-band features. These results clearly reveal intercalant-induced changes in the electronic structure of the layered nitride chlorides. From these results, we propose non-rigid band like behavior for this system in contrast to generally expected rigid-band filling upon intercalation. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:127 / 129
页数:3
相关论文
共 9 条
[1]   Spectrometer for polarized soft X-ray Raman scattering [J].
Harada, Y ;
Ishii, H ;
Fujisawa, M ;
Tezuka, Y ;
Shin, S ;
Watanabe, M ;
Kitajima, Y ;
Yagishita, A .
JOURNAL OF SYNCHROTRON RADIATION, 1998, 5 :1013-1015
[2]   Superconductivity of alkali metal intercalated beta-zirconium nitride chloride, A(x)ZrNCl (A = Li, Na, K) [J].
Kawaji, H ;
Hotehama, K ;
Yamanaka, S .
CHEMISTRY OF MATERIALS, 1997, 9 (10) :2127-2130
[3]   Resonant inelastic x-ray scattering spectra for electrons in solids [J].
Kotani, A ;
Shin, S .
REVIEWS OF MODERN PHYSICS, 2001, 73 (01) :203-246
[4]   Structural study on novel two-dimensional superconductor NaxHfNCl [J].
Shamoto, S ;
Iizawa, K ;
Yamada, M ;
Ohoyama, K ;
Yamaguchi, Y ;
Kajitani, T .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1999, 60 (8-9) :1431-1433
[5]  
SHAMOTO S, 2000, MOL CRYST LIQ CRYS A, V341, P515
[6]  
WATANABE M, 1997, P SOC PHOTO-OPT INS, V58, P3150
[7]   Superconductivity at 25.5 K in electron-doped layered hafnium nitride [J].
Yamanaka, S ;
Hotehama, K ;
Kawaji, H .
NATURE, 1998, 392 (6676) :580-582
[8]   High-Tc superconductivity in electron-doped layer structured nitrides [J].
Yamanaka, S .
ANNUAL REVIEW OF MATERIALS SCIENCE, 2000, 30 :53-82
[9]  
Yokoya T., 2001, PHYS REV B, V64