Infrared Spectra and Hydrogen-Bonded Network Structures of Large Protonated Water Clusters H+(H2O)n (n=20-200)

被引：88
|
作者：
Mizuse, Kenta [1 ]
Mikami, Naohiko [1 ]
Fujii, Asuka [1 ]
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 52期
关键词：
density functional calculations; hydrogen bonds; IR spectroscopy; mass spectrometry; water chemistry; LIQUID WATER; ICE; SPECTROSCOPY; SURFACES; SIZE; SIGNATURES; (H2O)(N); H2O;
D O I：
10.1002/anie.201003662
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Precisely size-selected protonated water clusters H+(H 2O)n (n=20-200) were studied by IR spectroscopy to provide insights into the structures of large-scale H-bonded water networks. The spectral features reveal that cluster structures gradually approach that of the bulk-water network and involve a greater number of four-coordinate water molecules with increasing cluster size (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10119 / 10122
页数：4
相关论文
共 50 条
  • [31] SIZE-SPECIFIC INFRARED-SPECTRA OF BENZENE-(H2O)(N) CLUSTERS (N=1 THROUGH 7) - EVIDENCE FOR NONCYCLIC (H2O)(N) STRUCTURES
    PRIBBLE, RN
    ZWIER, TS
    SCIENCE, 1994, 265 (5168) : 75 - 79
  • [32] STRUCTURES OF ANION WATER CLUSTERS - H-(H2O)N, N = 1-3
    XANTHEAS, SS
    DUNNING, TH
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (19): : 7505 - 7506
  • [33] Structural and dynamical characteristics of mesoscopic H+[H2O]n clusters
    Galvagno, Mariano
    Laria, Daniel
    Rodriguez, Javier
    JOURNAL OF MOLECULAR LIQUIDS, 2007, 136 (03) : 317 - 322
  • [34] MECHANISM OF THE FORMATION OF H+(H2O)N.OH CLUSTERS
    ARIFOV, UA
    POZHAROV, SL
    HIGH ENERGY CHEMISTRY, 1978, 12 (05) : 327 - 331
  • [35] Global Minima of Protonated Water Clusters (H2O)20H+ Revisited
    Parkkinen, P.
    Riikonen, S.
    Halonen, L.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 116 (44): : 10826 - 10835
  • [36] Enumeration of topology-distinct structures and possible stable structures of protonated water clusters, H3O+ (H2O) n-1 (n ≤ 5)
    Jieli, Maihemutijiang
    Miyake, Toshiko
    Aida, Misako
    Bulletin of the Chemical Society of Japan, 2007, 80 (11): : 2131 - 2136
  • [37] Enumeration of topology-distinct structures and possible stable structures of protonated water clusters, H3O+(H2O)n-1 (n ≤ 5)
    Jieli, Maihemutijiang
    Miyake, Toshiko
    Aida, Misako
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, 80 (11) : 2131 - 2136
  • [38] Structures and energetics of proton-bound formic acid-water clusters, (HCOOH)(n)(H2O)H+
    Aviyente, V
    Zhang, R
    Varnali, T
    Lifshitz, C
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1997, 161 (1-3): : 123 - 132
  • [39] Structures and energetics of proton-bound formic acid-water clusters, (HCOOH)n(H2O)H+
    Aviyente, V.
    Zhang, R.
    Varnali, T.
    Lifshitz, C.
    International Journal of Mass Spectrometry and Ion Processes, 161 (1/3):
  • [40] LARGE PROTONATED WATER CLUSTERS H+(H2O)N (1-LESS-THAN-OR-EQUAL-TO-N-GREATER-THAN-60) - THE PRODUCTION AND REACTIVITY OF CLATHRATE-LIKE STRUCTURES UNDER THERMAL CONDITIONS
    YANG, XL
    CASTLEMAN, AW
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (17) : 6845 - 6846
12345