Infrared Spectra and Hydrogen-Bonded Network Structures of Large Protonated Water Clusters H+(H2O)n (n=20-200)

被引：88
|
作者：
Mizuse, Kenta [1 ]
Mikami, Naohiko [1 ]
Fujii, Asuka [1 ]
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 52期
关键词：
density functional calculations; hydrogen bonds; IR spectroscopy; mass spectrometry; water chemistry; LIQUID WATER; ICE; SPECTROSCOPY; SURFACES; SIZE; SIGNATURES; (H2O)(N); H2O;
D O I：
10.1002/anie.201003662
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Precisely size-selected protonated water clusters H+(H 2O)n (n=20-200) were studied by IR spectroscopy to provide insights into the structures of large-scale H-bonded water networks. The spectral features reveal that cluster structures gradually approach that of the bulk-water network and involve a greater number of four-coordinate water molecules with increasing cluster size (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10119 / 10122
页数：4
相关论文
共 50 条
  • [21] Size-dependent reaction cross section of protonated water clusters H+(H2O)n (N=2-11) with D2O
    Yamaguchi, S
    Kudoh, S
    Okada, Y
    Orii, T
    Takeuchi, K
    Ichikawa, T
    Nakai, H
    JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (50): : 10904 - 10910
  • [22] Multiphoton ionization and ab initio calculation studies of the hydrogen-bonded clusters C4H5N-(H2O)n
    Li, Y
    Liu, XH
    Wang, XY
    Lou, NQ
    JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (15): : 2572 - 2579
  • [23] Reactions of water clusters H+(H2O)(n), n=3-75, with diethyl ether
    Schindler, T
    Berg, C
    NiednerSchatteburg, G
    Bondybey, VE
    CHEMICAL PHYSICS, 1995, 201 (2-3) : 491 - 496
  • [24] Microhydrated clusters of a pharmaceutical drug: infrared spectra and structures of amantadineH+(H2O)n
    George, Martin Andreas Robert
    Dopfer, Otto
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (07) : 5529 - 5549
  • [25] Anharmonic vibrational spectroscopy of hydrogen-bonded systems directly computed from ab initio potential surfaces:: (H2O)n, n=2, 3;: Cl-(H2O)n, n=1, 2;: H+(H2O)n, n=1, 2; H2O-CH3OH
    Chaban, GM
    Jung, JO
    Gerber, RB
    JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (12): : 2772 - 2779
  • [26] THEORETICAL-STUDIES OF THE CLATHRATE STRUCTURES OF (H2O)(20), H+(H2O)(20) AND H+(H2O)(21)
    KHAN, A
    CHEMICAL PHYSICS LETTERS, 1994, 217 (04) : 443 - 450
  • [27] Evolution of Hydrogen-Bond Networks in Protonated Water Clusters H+(H2O)n (n=1 to 120) Studied by Cryogenic Ion Mobility-Mass Spectrometry
    Servage, Kelly A.
    Silveira, Joshua A.
    Fort, Kyle L.
    Russell, David H.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (11): : 1825 - 1830
  • [28] MECHANISM OF FORMATION OF CHARGED WATER CLUSTERS H+(H2O)N AND (H2O)N+ FROM THE ICE DUE TO FAST ELECTRONS
    AVDIEV, EG
    BOGOLYUBOV, GM
    GEOMAGNETIZM I AERONOMIYA, 1990, 30 (03): : 463 - 468
  • [29] Comprehensive Analysis of the Hydrogen Bond Network Morphology and OH Stretching Vibrations in Protonated Methanol-Water Mixed Clusters, H+(MeOH)1(H2O)n (n=1-8)
    Kuo, Jer-Lai
    xie, Zhi-zhong
    Bing, Dan
    Fujii, Asuka
    Hamashima, Toru
    Suhara, Ken-ichiro
    Mikami, Naohiko
    JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (41): : 10125 - 10133
  • [30] STRUCTURE OF H+(H2O)N CLUSTERS NEAR THE MAGIC NUMBER N=21
    KOZACK, RE
    JORDAN, PC
    JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (04): : 2978 - 2984
12345