Progress in the Synthesis of C(sp2)-C(sp3) Bond by Reductive Heck Reactions of Alkenes

被引：3
|
作者：
Xiao, Xiao [1 ]
Liu, Jianchao [1 ]
机构：
[1] Jiangxi Normal Univ, Natl Engn Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 41卷 / 09期
基金：
中国国家自然科学基金;
关键词：
alkene; transition-metal catalysis; reductive Heck reaction; C(sp(2))-C(sp(3)) formation; PALLADIUM-CATALYZED REACTIONS; ARYL IODIDES; CONJUGATE ADDITION; EFFICIENT APPROACH; COUPLING REACTIONS; RING-SYSTEM; NANOPARTICLES; INDOLES; ENONES; FUNCTIONALIZATION;
D O I：
10.6023/cjoc202105016
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transition-metal catalyzed C(sp(2)) - C(sp(3)) cross-coupling is of great significance in organic chemistry for synthesizing complex natural products and pharmaceutical molecules. Recently, reductive Heck reactions have emerged as one of the simple and efficient strategies for the construction of C(sp(2)) - C(sp(3)) bond. The recent advances in the reductive Heck reactions of alkenes are summarized on the basis of different hydride sources. The related mechanisms are provided, and the future development of this field is also prospected.
引用
收藏
页码：3349 / 3365
页数：17
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