Pillar[6]quinone: facile synthesis, crystal structures and electrochemical properties

被引：8

作者：

Hirohata, Tomoki ^{[1
]}

Shida, Naoki ^{[1
]}

Uekusa, Hidehiro ^{[2
]}

Yasuda, Nobuhiro ^{[3
]}

Nishihara, Hirotomo ^{[4
]}

Ogoshi, Tomoki ^{[5
]}

Tomita, Ikuyoshi ^{[1
]}

Inagi, Shinsuke ^{[1
,6
]}

机构：

[1] Tokyo Inst Technol, Sch Mat & Chem Technol, Dept Chem Sci & Engn, Midori Ku, 4259 Nagatsuta Cho, Yokohama, Kanagawa 2268502, Japan

[2] Tokyo Inst Technol, Sch Sci, Dept Chem, Meguro Ku, 2-12-1 Oakayama, Tokyo 1528551, Japan

[3] Japan Synchrotron Radiat Res Inst, Diffract & Scattering Div, 1-1-1 Kouto, Sayo, Hyogo 6795198, Japan

[4] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Adv Inst Mat Res WPI AIMR, Aoba Ku, 2-1-1 Katahira, Sendai, Miyagi 9808577, Japan

[5] Kyoto Univ, Grad Sch Engn, Dept Synthet & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[6] Japan Sci & Technol Agcy JST, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 52期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

D O I：

10.1039/d1cc02413b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel electron-deficient macrocycle, pillar[6]quinone (P[Q](6)), has been synthesized for the first time by both chemical and electrochemical oxidation of pillar[6]arene, showing clear hexagonal columnar stacking in the solid state. Cathodic voltammetric studies of P[Q](6) revealed that three electrons are injected first, followed by stepwise one-electron reductions.

引用

页码：6360 / 6363

页数：4

共 22 条

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