Review: the development and applications of thermally assisted hydrolysis and methylation reactions

被引：262

作者：

Challinor, JM ^{[1
]}

机构：

[1] Chem Ctr WA, Forens Sci Lab, Perth, WA 6004, Australia

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2001年 / 61卷 / 1-2期

关键词：

thermally assisted hydrolysis and methylation; thermochemolysis; tetramethylammonium hydroxide; pyrolysis; gas chromatography-mass spectrometry; synthetic resins; natural resins; lipids; waxes; wood; polysaccharides; proteins; soil; humic substances; sediments; kerogen; dyes;

D O I：

10.1016/S0165-2370(01)00146-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This review outlines the developments of the thermally assisted hydrolysis and methylation (THM) technique in analytical pyrolysis over the past 12 years. The principal reagent used to effect the thermochemolysis reaction is tetramethylammonium hydroxide (TMAH) but the use of other quaternary ammonium hydroxides is discussed. The mechanisms of the reaction and the effect of experimental variables are also incorporated. The wide variety of applications reviewed include synthetic and natural resins, lipids, waxes, wood products, polysaccharides, proteins, soil and humic substances, sediments, kerogen and dyes. On-line and off-line THM reactions are involved. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：3 / 34

页数：32

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