Electron-transfer induced isomerizations of coordination compounds

被引：81
作者：
Pombeiro, AJL [1 ]
da Silva, MFCG [1 ]
Lemos, MANDA [1 ]
机构：
[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal
来源：
COORDINATION CHEMISTRY REVIEWS | 2001年 / 219卷
关键词：
molecular electrochemistry; redox processes; electron-transfer; isomerization; mechanisms; octahedral complexes;
D O I：
10.1016/S0010-8545(01)00299-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Geometrical isomerization processes induced electrochemically are reviewed for octahedral-type complexes, in particular with pi -electron acceptor ligands, with focus on those whose mechanisms have been established in terms of square ECEC-type schemes and electron-transfer chain catalysis. Rationalizations based on the isomeric redox potential differentiation are also presented. (C) 2001 Elsevier Science B.V. All rights reserved.
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收藏
页码：53 / 80
页数：28
相关论文
共 86 条
  • [1] MECHANISTIC STUDIES ON TRANS-DICARBONYL PHOSPHINE COMPLEXES OF MOLYBDENUM(I)
    ABDELHAMID, R
    ELSAMAHY, AA
    RABIA, MKM
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (02) : 321 - 325
  • [2] ACEWGODA GM, 1982, J CHEM SOC CHEM COMM, P284
  • [3] ELECTROCHEMICAL CARBONYLATION OF ORGANOIRON METHYL COMPLEX - A STUDY OF REACTION INTERMEDIATES
    AMATORE, C
    BAYACHOU, M
    VERPEAUX, JN
    POSPISIL, L
    FIEDLER, J
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 387 (1-2): : 101 - 108
  • [4] TRACE CROSSINGS IN CYCLIC VOLTAMMETRY AND ELECTROCHEMIC ELECTROCHEMICAL INDUCEMENT OF CHEMICAL-REACTIONS - AROMATIC NUCLEOPHILIC-SUBSTITUTION
    AMATORE, C
    PINSON, J
    SAVEANT, JM
    THIEBAULT, A
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 107 (01): : 59 - 74
  • [5] INTERCONVERSION OF PLANAR AND NONPLANAR N-AMIDO LIGANDS - THERMODYNAMICALLY STABLE NONPLANAR N-AMIDO LIGANDS
    ANSON, FC
    COLLINS, TJ
    GIPSON, SL
    KEECH, JT
    KRAFFT, TE
    PEAKE, GT
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (21) : 6593 - 6605
  • [6] ELECTRON-TRANSFER CHAIN CATALYSIS IN ORGANOTRANSITION METAL CHEMISTRY
    ASTRUC, D
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (05): : 643 - 660
  • [7] Astruc D., 1995, ELECT TRANSFER RADIC
  • [8] CHEMICAL AND ELECTROCHEMICAL OXIDATION OF MER FAC-CR(CO)3(ETA-1-L-L)(ETA-2-L-L) CONTAINING A PENDANT DONOR ATOM - ESR STUDIES OF THE CATIONS MER-[CR(CO)3(ETA-1-L-L)(ETA-2-L-L)]+ AND TRANS-[CR(CO)2(ETA-2-L-L)2]+ (L-L = BIDENTATE GROUP-15 LIGAND)
    BAGCHI, RN
    BOND, AM
    COLTON, R
    CREECE, I
    MCGREGOR, K
    WHYTE, T
    [J]. ORGANOMETALLICS, 1991, 10 (08) : 2611 - 2615
  • [9] SYNTHESIS AND OXIDATION OF CATIONIC HETEROBINUCLEAR CYANIDE-BRIDGED COMPLEXES OF MANGANESE AND IRON
    BARRADO, G
    CARRIEDO, GA
    DIAZVALENZUELA, C
    RIERA, V
    [J]. INORGANIC CHEMISTRY, 1991, 30 (23) : 4416 - 4420
  • [10] Basolo F., 1967, Mechanisms of Inorganic Reactions, pXi + 701
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