Cobalt-CatalyzedZtoEGeometrical Isomerization of 1,3-Dienes

被引：13

作者：

Wang, Wei ^{[1
]}

He, Shuying ^{[1
]}

Zhong, Yuqing ^{[1
]}

Chen, Jianhui ^{[1
]}

Cai, Cheng ^{[1
]}

Luo, Yanshu ^{[1
]}

Xia, Yuanzhi ^{[1
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 87卷 / 07期

关键词：

DOUBLE-BOND ISOMERIZATION; ALKENE ISOMERIZATION; PALLADIUM(II)-CATALYZED ISOMERIZATION; STEREOSELECTIVE-SYNTHESIS; ASYMMETRIC HYDROGENATION; CATALYZED ISOMERIZATION; PALLADIUM; IRON; COMPLEXES; MECHANISM;

D O I：

10.1021/acs.joc.1c03164

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient cobalt-catalyzed geometrical isomerization of1,3-dienes is described. In the combination of a CoCl2precatalyst with anamido-diphosphine-oxazoline ligand, the geometrical isomerization ofE/Zmixtures of 1,3-dienes proceed in a stereoconvergent manner, affording (E)isomers in high stereoselectivity. This facile transformation features a broadsubstrate scope with good functional group tolerance and could be scaled up to the gram scale smoothly with a catalyst loading of 1mol %.

引用

页码：4712 / 4723

页数：12

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