Insight into ultra-flexible & robust silica aerogels based on diene synthesis reaction: Preparation and oil/water separation

被引：18

作者：

Du, Chunhua ^{[1
]}

Chen, Yue ^{[1
]}

He, Song ^{[1
]}

Ruan, Chichi ^{[1
]}

Liu, Xinyu ^{[1
]}

He, Chunxiang ^{[1
]}

Jin, Xin ^{[1
]}

Chen, Qilin ^{[1
]}

Ma, Yuansheng ^{[1
]}

Chen, Guanyu ^{[1
]}

机构：

[1] Wuhan Univ Technol, Sch Safety Sci & Emergency Management, Luoshi Rd 122, Wuhan 430070, Peoples R China

来源：

APPLIED SURFACE SCIENCE | 2022年 / 606卷

关键词：

Silica aerogels; Diene synthesis reaction; Ultra-flexibility; Super hydrophobicity; Oil/water separation; METHYLTRIMETHOXYSILANE; XEROGELS;

D O I：

10.1016/j.apsusc.2022.154902

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper reported the preparation of ultra-flexible silica aerogels based on diene synthesis reaction at atmospheric pressure. Vinyl trimethoxy silane and vinyl methyl dimethoxy silane as silicon source were used to prepare vinyl aerogels by one-pot acid-base sol-gel route. The diene synthesis reaction was used to prepare ultra -flexible and super hydrophobic silica aerogels on the basis of vinyl aerogels. Maximum strain of the ultra-flexible aerogels is as high as 90 % for 20 compression-decompression cycles. The aerogels can be recovered completely without structure destruction. In addition, the adsorption capacity of the samples is higher than that of the conventional silica aerogels, which can reach to 15.0 g.g(-1) of dichloromethane. It is worth noting that they also have efficient cycle performance for adsorption and filtration. Acting as core part of filtration, the organic sol-vents insoluble in water can be easily separated from water by the aerogels.

引用

页数：11

共 42 条

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