Lipophilic Corrole-Porphyrin-Corrole Linear Triad

被引:2
作者
Jiang, Hao [1 ]
Dong, Xinyi [2 ]
Zhu, Weihua [2 ]
Liang, Xu [2 ]
Xu, Haijun [1 ,3 ]
机构
[1] Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Jiangsu Key Lab Biomass Based Green Fuels & Chem, Nanjing 210037, Peoples R China
[2] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[3] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
来源
MACROHETEROCYCLES | 2021年 / 14卷 / 03期
基金
中国国家自然科学基金;
关键词
Porphyrin; corrole; electronic structure; spectroscopy; electrochemistry; ELECTRONIC-STRUCTURE; BISCORROLES; COMPLEXES; BINDING;
D O I
10.6060/mhc210842j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, a novel lipophilic corrole-porphyrin-corrole triad has been synthesized and characterized. The electronic structure study was carried out by the spectroscopic investigations and electrochemical characterizations to provide better understanding of the electronic structure of this novel macrocyclic linear triad. In addition, the triad exhibits a highly efficient energy transfer process from the excited porphyrin part to the corrole core units.
引用
收藏
页码:214 / 220
页数:7
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