Synthesis and resolution of racemic 2-amino-2'-hydroxy-1,1'-binaphthyl

被引：46
|
作者：
Smrcina, M [1 ]
Vyskocil, S [1 ]
Polivkova, J [1 ]
Polakova, J [1 ]
Kocovsky, P [1 ]
机构：
[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1996年 / 61卷 / 10期
关键词：
binaphthyls; oxidative coupling; resolution;
D O I：
10.1135/cccc19961520
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound 3 has been prepared via a highly selective, Cu(II)-mediated cross-coupling of 2-aminonaphthalene 1 and 2-naphthol 2 and resolved into enantiomers via crystallization of diastereoisomeric salts with (1S)-(+)-10-camphorsulfonic acid. The method has been optimized and the use of chromatography eliminated.
引用
收藏
页码：1520 / 1524
页数：5
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