Synthesis and resolution of racemic 2-amino-2'-hydroxy-1,1'-binaphthyl

被引：46

作者：

Smrcina, M ^{[1
]}

Vyskocil, S ^{[1
]}

Polivkova, J ^{[1
]}

Polakova, J ^{[1
]}

Kocovsky, P ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1996年 / 61卷 / 10期

关键词：

binaphthyls; oxidative coupling; resolution;

D O I：

10.1135/cccc19961520

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound 3 has been prepared via a highly selective, Cu(II)-mediated cross-coupling of 2-aminonaphthalene 1 and 2-naphthol 2 and resolved into enantiomers via crystallization of diastereoisomeric salts with (1S)-(+)-10-camphorsulfonic acid. The method has been optimized and the use of chromatography eliminated.

引用

页码：1520 / 1524

页数：5

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