Two-step solid-state synthesis of PEPPSI-type compounds

被引：38

作者：

Adams, Christopher J. ^{[1
]}

Lusi, Matteo ^{[1
]}

Mutambi, Emily M. ^{[1
]}

Orpen, A. Guy ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 47期

关键词：

CROSS-COUPLING CATALYST; COMPLEXES; PRECATALYST; SALTS; NHC;

D O I：

10.1039/c5cc02924d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.

引用

页码：9632 / 9635

页数：4

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