Two-step solid-state synthesis of PEPPSI-type compounds

被引：39

作者：

Adams, Christopher J. ^{[1
]}

Lusi, Matteo ^{[1
]}

Mutambi, Emily M. ^{[1
]}

Orpen, A. Guy ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 47期

关键词：

CROSS-COUPLING CATALYST; COMPLEXES; PRECATALYST; SALTS; NHC;

D O I：

10.1039/c5cc02924d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.

引用

页码：9632 / 9635

页数：4

共 23 条

[1] Solid-state interconversions of coordination networks and hydrogen-bonded salts [J].

Adams, Christopher J. ;

Colquhoun, Howard M. ;

Crawford, Paul C. ;

Lusi, Matteo ;

Orpen, A. Guy .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (07) :1124-1128

[2] Crystal synthesis of 1,4-phenylenediamine salts and coordination networks [J].

Adams, Christopher J. ;

Haddow, Mairi F. ;

Lusi, Matteo ;

Orpen, A. Guy .

CRYSTENGCOMM, 2011, 13 (13) :4324-4331

[3] Coordination chemistry of platinum and palladium in the solid-state: Synthesis of imidazole and pyrazole complexes [J].

Adams, Christopher J. ;

Haddow, Mairi F. ;

Hughes, Robert J. I. ;

Kurawa, Mukhtar A. ;

Orpen, A. Guy .

DALTON TRANSACTIONS, 2010, 39 (15) :3714-3724

[4] Solid state synthesis of coordination compounds from basic metal salts [J].

Adams, Christopher J. ;

Kurawa, Mukhtar A. ;

Lusi, Matteo ;

Orpen, A. Guy .

CRYSTENGCOMM, 2008, 10 (12) :1790-1795

[5]

[Anonymous], 2009, CRYSTENGCOMM, p[375, 522]

[6]

[Anonymous], 2011, CRYSTENGCOMM DYNAMIC, p[4291, 4438]

[7] Imidazolylidenes, imidazolinylidenes and imidazolidines [J].

Arduengo, AJ ;

Krafczyk, R ;

Schmutzler, R ;

Craig, HA ;

Goerlich, JR ;

Marshall, WJ ;

Unverzagt, M .

TETRAHEDRON, 1999, 55 (51) :14523-14534

[8] Organometallic chemistry in the solid state [J].

Coville, NJ ;

Cheng, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 571 (02) :149-169

[9] METAL-COMPLEXES OF N-HETEROCYCLIC CARBENES - A NEW STRUCTURAL PRINCIPLE FOR CATALYSTS IN HOMOGENEOUS CATALYSIS [J].

HERRMANN, WA ;

ELISON, M ;

FISCHER, J ;

KOCHER, C ;

ARTUS, GRJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2371-2374

[10] HYDROGEN-BOND ACCEPTOR ABILITIES OF TETRACHLOROMETALATE(II) COMPLEXES IN IONIC LIQUIDS [J].

HITCHCOCK, PB ;

SEDDON, KR ;

WELTON, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (17) :2639-2643

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