Chemical bonding in complexes with high coordination numbers: a charge density study

被引：14

作者：

Borissova, Alexandra O. ^{[1
]}

Lyssenko, Konstantin A. ^{[1
]}

机构：

[1] Russian Acad Sci, Xray Struct Ctr, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2011年 / 21卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

TOPOLOGICAL ANALYSIS; HYDROGEN-BOND; ELECTRON; ENERGY; CRYSTAL; GEOMETRY; CLUSTERS; ALKANES; QTAIM;

D O I：

10.1016/j.mencom.2011.04.017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The topological analysis of an experimental charge-density distribution in crystalline tris(pyridine)bis(o-hydroxybenzoato)cadmium(II) revealed that the metal-ligand bonds occupy nearly the same place in the energetic scale as the hydrogen bonds do, thus being extremely sensitive to steric and crystal-packing effects.

引用

页码：160 / 162

页数：3

共 40 条

[1]

[Anonymous], XD COMPUTER PROGRAM

[2]

[Anonymous], MENDELEEV COMMUN

[3]

[Anonymous], **NON-TRADITIONAL**

[4]

[Anonymous], The Cambridge Crystallographic Centre via

[5]

Bader R. F. W., 1994, ATOMS MOL QUANTUM TH

[6] Estimation of Dissociation Energy in Donor-Acceptor Complex AuCl•PPh3 via Topological Analysis of the Experimental Electron Density Distribution Function [J].

Borissova, Alexandra O. ;

Korlyukov, Alexander A. ;

Antipin, Mikhail Yu. ;

Lyssenko, Konstantin A. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (46) :11519-11522

[7] Mutual Influence of Cyclopentadienyl and Carbonyl Ligands in Cymantrene: QTAIM Study [J].

Borissova, Alexandra O. ;

Antipin, Mikhail Yu ;

Lyssenko, Konstantin A. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (40) :10845-10851

[8]

CHAGAS AP, 1989, POLYHEDRON, V8, P1093

[9] PENTAGONAL-BIPYRAMID GEOMETRY AND CD-113 NMR CHEMICAL-SHIFTS - CRYSTAL-STRUCTURES AND SOLUTION AND SOLID-STATE CD-113 NMR OF BIS(MU-ORTHO-HYDROXYBENZOATO)BIS(ORTHO-HYDROXYBENZOATO)TETRAAQUODICADMIUM(II) AND TRIS(PYRIDINE)BIS(ORTHO-HYDROXYBENZOATO)CADMIUM(II) [J].

CHARLES, NG ;

GRIFFITH, EAH ;

RODESILER, PF ;

AMMA, EL .

INORGANIC CHEMISTRY, 1983, 22 (19) :2717-2723

[10] Trans-effects in octahedral transition metal complexes [J].

Coe, BJ ;

Glenwright, SJ .

COORDINATION CHEMISTRY REVIEWS, 2000, 203 :5-80

← 1 2 3 4 →