Significant enhancement of the NO2 sensing capability in networked SnO2 nanowires by Au nanoparticles synthesized via γ-ray radiolysis

被引:59
作者
Choi, Sun-Woo [1 ]
Jung, Sung-Hyun [1 ]
Kim, Sang Sub [1 ]
机构
[1] Inha Univ, Sch Mat Sci & Engn, Inchon 402751, South Korea
基金
新加坡国家研究基金会;
关键词
Au nanoparticles; gamma-Ray radiolysis; Functionalization; SnO2; nanowires; Gas sensors; GOLD NANOPARTICLES; GAS SENSORS; COMPOSITE NANOPARTICLES; CARBON NANOTUBES; CO; PARTICLES; GROWTH; OXIDES;
D O I
10.1016/j.jhazmat.2011.07.053
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
gamma-Ray radiolysis was applied to the synthesis of Au nanoparticles. The growth behavior of Au nanoparticles was systematically investigated as a function of the processing parameters under gamma-ray radiolysis. The surface of the networked SnO2 nanowires fabricated through the vapor-phase selective growth process was uniformly functionalized with the Au nanoparticles by the gamma-ray radiolysis process. Au nanoparticle-functionalized SnO2 nanowires were compared to bare SnO2 nanowires in terms of the NO2 sensing characteristics. Au functionalization sharply improved the sensitivity and response time of SnO2 nanowire-based gas sensors, most likely due to the spillover and the catalytic effects of Au nanoparticles. The methodology used in this work can be easily extended to synthesize various combinations of metal nanoparticles and oxide nanowires, which may be useful materials for use in detecting hazardous substances. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:243 / 248
页数:6
相关论文
共 27 条
[1]   Enhanced CO sensitivity and selectivity of gold nanoparticles-doped SnO2 sensor in presence of propane and methane [J].
Bahrami, B. ;
Khodadadi, A. ;
Kazemeini, M. ;
Mortazavi, Y. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 133 (01) :352-356
[2]   Nucleation, growth and properties of nanoclusters studied by radiation chemistry - Application to catalysis [J].
Belloni, J .
CATALYSIS TODAY, 2006, 113 (3-4) :141-156
[3]   H2S Detection by Vertically Aligned CuO Nanowire Array Sensors [J].
Chen, Jiajun ;
Wang, Kai ;
Hartman, Lisa ;
Zhou, Weilie .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (41) :16017-16021
[4]   Conduction and gas-surface reaction modeling in metal oxide gas sensors [J].
Chwieroth, B ;
Patton, BR ;
Wang, YZ .
JOURNAL OF ELECTROCERAMICS, 2001, 6 (01) :27-41
[5]   Homogeneous coating of Au and SnO2 nanocrystals on carbon nanotubes via layer-by-layer assembly: a new ternary hybrid for a room-temperature CO gas sensor [J].
Du, Ning ;
Zhang, Hui ;
Ma, Xiangyang ;
Yang, Deren .
CHEMICAL COMMUNICATIONS, 2008, (46) :6182-6184
[6]  
ERSHOV G, 1993, J PHYS CHEM-US, V97, P3434
[7]   Radiation-induced and chemical formation of gold clusters [J].
Gachard, E ;
Remita, H ;
Khatouri, J ;
Keita, B ;
Nadjo, L ;
Belloni, J .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (11) :1257-1265
[8]   Radiolytic preparation of ultrafine colloidal gold particles in aqueous solution: Optical spectrum, controlled growth, and some chemical reactions [J].
Henglein, A .
LANGMUIR, 1999, 15 (20) :6738-6744
[9]   Room-temperature H2S gas sensing at ppb level by single crystal In2O3 whiskers [J].
Kaur, Manmeet ;
Jain, Namrata ;
Sharma, Kamalkant ;
Bhattacharya, Shovit ;
Roy, Mainak ;
Tyagi, A. K. ;
Gupta, S. K. ;
Yakhmi, J. V. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 133 (02) :456-461
[10]   Fabrication of metal-shelled coaxial nanowires and annealing-induced formation of metal nanoparticles for catalytic applications: Growth and characteristics of SnO2-branched nanostructures [J].
Kim, Hyo Sung ;
Park, Sang Eon ;
Kim, Hyoun Woo ;
Park, Jae Young ;
Jiang, Nanzhe ;
Kim, Sang Sub .
SOLID STATE SCIENCES, 2010, 12 (06) :970-977