A new method for the generation of α-nitrosoolefins from ketooximes and its application to the synthesis of 5,6-dihydro-4H-1,2-oxazine derivatives

被引：15

作者：

Gaonkar, SL ^{[1
]}

Rai, KML ^{[1
]}

机构：

[1] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2005年 / 42卷 / 05期

关键词：

D O I：

10.1002/jhet.5570420520

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of ketooximes containing alpha-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of alpha-nitrosoolefins via alpha-nitrosochloride, which can react in situ intermolecularly with olefinic compounds to produce 5,6-dihydro-4H-1,2-oxazine derivatives in good yield.

引用

页码：877 / 881

页数：5

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