Dynamic Microcontact Printing for Patterning Polymer-Brush Microstructures

被引:30
作者
Chen, Tao [1 ]
Jordan, Rainer [1 ]
Zauscher, Stefan [2 ,3 ]
机构
[1] Tech Univ Dresden, Dept Chem, D-01069 Dresden, Germany
[2] Duke Univ, Ctr Biol Inspired Mat & Mat Syst, Durham, NC 27708 USA
[3] Duke Univ, Dept Mech Engn & Mat Sci, Durham, NC 27708 USA
基金
美国国家科学基金会;
关键词
SELF-ASSEMBLED MONOLAYERS; SURFACE-INITIATED POLYMERIZATION; AMPLIFICATION; LITHOGRAPHY;
D O I
10.1002/smll.201100354
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A single, conventional poly(dimethylsiloxane) (PDMS) stamp is used under a dynamic microcontact printing (ÎCP) method, extended from a static one. This new approach is investigated and combined with surface-initiated atom-transfer radical polymerization (SI-ATRP) to fabricate complex patterned hierarchical and gradient polymer-brush microstructures with a number of different feature morphologies that do not exist on the original stamp without sophisticated instrumentation being necessary. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2148 / 2152
页数:5
相关论文
共 32 条
[1]   Electron-beam chemical lithography with aliphatic self-assembled monolayers [J].
Ballav, Nirmalya ;
Schilp, Soeren ;
Zharnikov, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (08) :1421-1424
[2]   Surface-grafted polymer gradients: Formation, characterization, and applications [J].
Bhat, Rajendra R. ;
Tomlinson, Michael R. ;
Wu, Tao ;
Genzer, Jan .
SURFACE- INITIATED POLYMERIZATION II, 2006, 198 :51-124
[3]   Extending micro-contact printing for patterning complex polymer brush microstructures [J].
Chen, Tao ;
Jordan, Rainer ;
Zauscher, Stefan .
POLYMER, 2011, 52 (12) :2461-2467
[4]   Stimulus-responsive polymer brushes on surfaces: Transduction mechanisms and applications [J].
Chen, Tao ;
Ferris, Robert ;
Zhang, Jianming ;
Ducker, Robert ;
Zauscher, Stefan .
PROGRESS IN POLYMER SCIENCE, 2010, 35 (1-2) :94-112
[5]   Fabrication of Micropatterned Stimulus-Responsive Polymer-Brush 'Anemone' [J].
Chen, Tao ;
Zhong, Jianming ;
Chang, Debby P. ;
Carcia, Andres ;
Zauscher, Stefan .
ADVANCED MATERIALS, 2009, 21 (18) :1825-+
[6]   Polymeric and biomacromolecular brush nanostructures: progress in synthesis, patterning and characterization [J].
Ducker, Robert ;
Garcia, Andres ;
Zhang, Jianming ;
Chen, Tao ;
Zauscher, Stefan .
SOFT MATTER, 2008, 4 (09) :1774-1786
[7]   Overpressure contact printing [J].
Guo, QJ ;
Teng, XW ;
Yang, H .
NANO LETTERS, 2004, 4 (09) :1657-1662
[8]  
Husemann M, 1999, ANGEW CHEM INT EDIT, V38, P647, DOI 10.1002/(SICI)1521-3773(19990301)38:5<647::AID-ANIE647>3.0.CO
[9]  
2-0
[10]   Surface-initiated free radical polymerization of polystyrene micropatterns on a self-assembled monolayer on gold [J].
Hyun, J ;
Chilkoti, A .
MACROMOLECULES, 2001, 34 (16) :5644-5652