Dynamic Microcontact Printing for Patterning Polymer-Brush Microstructures

被引:29
作者
Chen, Tao [1 ]
Jordan, Rainer [1 ]
Zauscher, Stefan [2 ,3 ]
机构
[1] Tech Univ Dresden, Dept Chem, D-01069 Dresden, Germany
[2] Duke Univ, Ctr Biol Inspired Mat & Mat Syst, Durham, NC 27708 USA
[3] Duke Univ, Dept Mech Engn & Mat Sci, Durham, NC 27708 USA
基金
美国国家科学基金会;
关键词
SELF-ASSEMBLED MONOLAYERS; SURFACE-INITIATED POLYMERIZATION; AMPLIFICATION; LITHOGRAPHY;
D O I
10.1002/smll.201100354
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A single, conventional poly(dimethylsiloxane) (PDMS) stamp is used under a dynamic microcontact printing (ÎCP) method, extended from a static one. This new approach is investigated and combined with surface-initiated atom-transfer radical polymerization (SI-ATRP) to fabricate complex patterned hierarchical and gradient polymer-brush microstructures with a number of different feature morphologies that do not exist on the original stamp without sophisticated instrumentation being necessary. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2148 / 2152
页数:5
相关论文
共 32 条
  • [1] Electron-beam chemical lithography with aliphatic self-assembled monolayers
    Ballav, Nirmalya
    Schilp, Soeren
    Zharnikov, Michael
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (08) : 1421 - 1424
  • [2] Surface-grafted polymer gradients: Formation, characterization, and applications
    Bhat, Rajendra R.
    Tomlinson, Michael R.
    Wu, Tao
    Genzer, Jan
    [J]. SURFACE- INITIATED POLYMERIZATION II, 2006, 198 : 51 - 124
  • [3] Extending micro-contact printing for patterning complex polymer brush microstructures
    Chen, Tao
    Jordan, Rainer
    Zauscher, Stefan
    [J]. POLYMER, 2011, 52 (12) : 2461 - 2467
  • [4] Stimulus-responsive polymer brushes on surfaces: Transduction mechanisms and applications
    Chen, Tao
    Ferris, Robert
    Zhang, Jianming
    Ducker, Robert
    Zauscher, Stefan
    [J]. PROGRESS IN POLYMER SCIENCE, 2010, 35 (1-2) : 94 - 112
  • [5] Fabrication of Micropatterned Stimulus-Responsive Polymer-Brush 'Anemone'
    Chen, Tao
    Zhong, Jianming
    Chang, Debby P.
    Carcia, Andres
    Zauscher, Stefan
    [J]. ADVANCED MATERIALS, 2009, 21 (18) : 1825 - +
  • [6] Polymeric and biomacromolecular brush nanostructures: progress in synthesis, patterning and characterization
    Ducker, Robert
    Garcia, Andres
    Zhang, Jianming
    Chen, Tao
    Zauscher, Stefan
    [J]. SOFT MATTER, 2008, 4 (09) : 1774 - 1786
  • [7] Overpressure contact printing
    Guo, QJ
    Teng, XW
    Yang, H
    [J]. NANO LETTERS, 2004, 4 (09) : 1657 - 1662
  • [8] Husemann M, 1999, ANGEW CHEM INT EDIT, V38, P647, DOI 10.1002/(SICI)1521-3773(19990301)38:5<647::AID-ANIE647>3.0.CO
  • [9] 2-0
  • [10] Surface-initiated free radical polymerization of polystyrene micropatterns on a self-assembled monolayer on gold
    Hyun, J
    Chilkoti, A
    [J]. MACROMOLECULES, 2001, 34 (16) : 5644 - 5652