Effect of Cu2+ substitution on the relaxor behavior of BaBi2Nb2O9 ferroelectric nanoceramics prepared by chemical route

被引：4

作者：

Adak, Mrinal K. ^{[1
]}

Mukherjee, Arnab ^{[1
]}

Chowdhury, Anirban ^{[1
]}

Khatun, Julekha ^{[1
]}

Dhak, Prasanta ^{[2
]}

Dhak, Debasis ^{[1
]}

机构：

[1] Sidho Kanho Birsha Univ, Dept Chem, Nanomat Res Lab, Purulia 723104, India

[2] Univ Oslo, Ctr Mat Sci & Nanotechnol Chem SMN, Dept Chem, Oslo, Norway

来源：

MATERIALS RESEARCH EXPRESS | 2019年 / 6卷 / 02期

关键词：

ferroelectricity; impedance; AC conductivity; density of states; energy storage density; ENERGY-STORAGE PROPERTIES; DIFFUSE PHASE-TRANSITION; DIELECTRIC-PROPERTIES; PIEZOELECTRIC CERAMICS; ELECTRICAL-PROPERTIES; AURIVILLIUS PHASES; BISMUTH TITANATE; THIN-FILMS; X-RAY; RELAXATION;

D O I：

10.1088/2053-1591/aae99a

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Ba0.5Cu0.5Bi2Nb2O9 (BCuBN) crystalline nano ceramics were prepared by chemical precursor solution decomposition method. A structure property correlation of BCuBN done through dielectric impedance, density of states, hopping mechanism and discharge polarization study after the incorporation of Jahn-Teller active Cu2+ (d(9), s = 1/2) ions. X-ray diffraction study, scanning electron microscopy demonstrated the orthorhombic structure with A21am space group of BCuBN. Ferroelectric to paraelectric phase transition temperature (T-c) obtained in the temperature range from 515 degrees C to 545 degrees C at different frequency range. The activation energy of relaxation behaviour in complex imaginary impedance plot with frequency is 0.80 eV closer to dc conductivity (0.73 eV). The frequency dependent ac conductivity becomes much higher at higher frequency. The density of states and hopping mechanism were successfully explained here. The field induced polarization hysteresis loops demonstrated the pseudo static saturation of polarization. Maximum discharge energy density was 1.12 J cm(-3) at 10 kV cm(-1) electric field.

引用

页数：17

共 83 条

[11] Structural investigations of copper doped B2O3-Bi2O3 glasses with high bismuth oxide content [J].