Direct observation of the labile imine formation through single-crystal-to-single-crystal reactions in the pores of a porous coordination network

被引：124

作者：

Haneda, Tsuyoshi ^{[1
,2
]}

Kawano, Masaki ^{[1
,2
]}

Kawamichi, Takehide ^{[1
,2
]}

Fujita, Makoto ^{[1
,2
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] JST, CREST, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 05期

关键词：

D O I：

10.1021/ja7111564

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report an approach to in situ observation of unstable species produced by a single-cystal-to single-crystal chemical reaction. We succeeded in uniform formation and the direct observation of unstable imines in pores of a 3-D porous coordination network with aldehydes provided by guest exchange. Moreover, we found the remarkable dynamic motion of a part of the host framework by changing aldehydes.

引用

页码：1578 / +

页数：3

共 30 条

[21] A two-in-one crystal: Uptake of two different guests into two distinct channels of a biporous coordination network [J].

Ohmori, O ;

Kawano, M ;

Fujita, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (13) :1962-1964

[22] Crystal-to-crystal guest exchange of large organic molecules within a 3D coordination network [J].

Ohmori, O ;

Kawano, M ;

Fujita, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (50) :16292-16293

[23] Asymmetric induction in organic photochemistry via the solid-state ionic chiral auxiliary approach [J].

Scheffer, JR ;

Xia, WJ .

ORGANIC SOLID STATE REACTIONS, 2005, 254 :233-262

[24] A homochiral metal-organic porous material for enantioselective separation and catalysis [J].

Seo, JS ;

Whang, D ;

Lee, H ;

Jun, SI ;

Oh, J ;

Jeon, YJ ;

Kim, K .

NATURE, 2000, 404 (6781) :982-986

[25] Solvent-free organic synthesis [J].

Tanaka, K ;

Toda, F .

CHEMICAL REVIEWS, 2000, 100 (03) :1025-1074

[26] Topotactic linear radical polymerization of divinylbenzenes in porous coordination polymers [J].

Uemura, Takashi ;

Hiramatsu, Daisuke ;

Kubota, Yoshiki ;

Takata, Masaki ;

Kitagawa, Susumu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (26) :4987-4990

[27] Postsynthetic covalent modification of a neutral metal-organic framework [J].

Wang, Zhenqiang ;

Cohen, Seth M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (41) :12368-+

[28] SOLID-STATE POLYMERIZATION MECHANISMS [J].

WEGNER, G .

PURE AND APPLIED CHEMISTRY, 1977, 49 (04) :443-454

[29] IMINE-ENAMINE SYSTEMS AND THE MECHANISM OF THEIR OXIDATION [J].

WITKOP, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (12) :2873-2882

[30] Reticular synthesis and the design of new materials [J].

Yaghi, OM ;

O'Keeffe, M ;

Ockwig, NW ;

Chae, HK ;

Eddaoudi, M ;

Kim, J .

NATURE, 2003, 423 (6941) :705-714

← 1 2 3 →