Direct observation of the labile imine formation through single-crystal-to-single-crystal reactions in the pores of a porous coordination network

被引：124

作者：

Haneda, Tsuyoshi ^{[1
,2
]}

Kawano, Masaki ^{[1
,2
]}

Kawamichi, Takehide ^{[1
,2
]}

Fujita, Makoto ^{[1
,2
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] JST, CREST, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 05期

关键词：

D O I：

10.1021/ja7111564

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report an approach to in situ observation of unstable species produced by a single-cystal-to single-crystal chemical reaction. We succeeded in uniform formation and the direct observation of unstable imines in pores of a 3-D porous coordination network with aldehydes provided by guest exchange. Moreover, we found the remarkable dynamic motion of a part of the host framework by changing aldehydes.

引用

页码：1578 / +

页数：3

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