Direct observation of the labile imine formation through single-crystal-to-single-crystal reactions in the pores of a porous coordination network

被引：123
作者：
Haneda, Tsuyoshi [1 ,2 ]
Kawano, Masaki [1 ,2 ]
Kawamichi, Takehide [1 ,2 ]
Fujita, Makoto [1 ,2 ]
机构：
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] JST, CREST, Bunkyo Ku, Tokyo 1138656, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 05期
关键词：
D O I：
10.1021/ja7111564
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report an approach to in situ observation of unstable species produced by a single-cystal-to single-crystal chemical reaction. We succeeded in uniform formation and the direct observation of unstable imines in pores of a 3-D porous coordination network with aldehydes provided by guest exchange. Moreover, we found the remarkable dynamic motion of a part of the host framework by changing aldehydes.
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页码：1578 / +
页数：3
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