Synthesis gas adjustment by low temperature sorption enhanced water-gas shift reaction through a copper-zeolite 13X hybrid material

被引：5
作者：
Cunha, Adelino F. [1 ]
Moreira, Miguel N. [1 ]
Ribeiro, Ana M. [1 ]
Loureiro, Jose M. [1 ]
Rodrigues, Alirio E. [1 ]
Terzan, Janvit [2 ]
Djinovic, Petar [2 ]
Pintar, Albin [2 ]
机构：
[1] Univ Porto, Fac Engn, Dept Chem Engn, Lab Separat & React Engn Associate Lab LSRE LCM, Rua Dr Roberto Frias, P-4200465 Oporto, Portugal
[2] Natl Inst Chem, Dept Environm Sci & Engn, Hajdrihova 19, SI-1001 Ljubljana, Slovenia
来源：
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION | 2017年 / 121卷
关键词：
PURITY HYDROGEN-PRODUCTION; CO2; CAPTURE; ADSORPTION EQUILIBRIUM; BINDERLESS BEADS; CARBON-DIOXIDE; HYDROTALCITE; ETHANOL; SORBENT; PERFORMANCE; EQUATIONS;
D O I：
10.1016/j.cep.2017.07.023
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Water-gas shift reaction (WGSR) and sorption enhanced water-gas shift reaction (SE-WGSR) were studied over Cu-zeolite 13X hybrid material (containing the catalyst and CO2 sorbent) in the temperature range between 398 and 548 K. The copper phase was deposited by wet impregnation of binderless beads of 13X zeolite. The catalysts were characterized by N-2 sorption, XRD, He pycnometry and SEM-EDX techniques. in addition, the Cu-zeolite 13X hybrid material was also compared with a previously prepared and examined hybrid material, Cu-hydrotalcite hybrid material, used for the same purpose, the SE-WGSR.
引用
收藏
页码：97 / 110
页数：14
相关论文
共 62 条
  • [1] Selection of CO2 chemisorbent for fuel-cell grade H2 production by sorption-enhanced water gas shift reaction
    Beaver, Michael G.
    Caram, Hugo S.
    Sircar, Shivaji
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (07) : 2972 - 2978
  • [2] Boyle G., 1996, Renewable energy: powerfor a sustainablefuture
  • [3] Broom DP, 2011, GREEN ENERGY TECHNOL, P1
  • [4] HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS
    Cavani, F.
    Trifiro, F.
    Vaccari, A.
    [J]. CATALYSIS TODAY, 1991, 11 (02) : 173 - 301
  • [5] Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13X at high pressures
    Cavenati, S
    Grande, CA
    Rodrigues, AE
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (04) : 1095 - 1101
  • [6] Simulation of Methane Steam Reforming Enhanced by in Situ CO2 Sorption Using K2CO3-Promoted Hydrotalcites for H2 Production
    Chanburanasiri, Naruewan
    Ribeiro, Ana M.
    Rodrigues, Alirio E.
    Laosiripojana, Navadol
    Assabumrungrat, Suttichai
    [J]. ENERGY & FUELS, 2013, 27 (08) : 4457 - 4470
  • [7] METHANOL SYNTHESIS REACTIONS - CALCULATIONS OF EQUILIBRIUM CONVERSIONS USING EQUATIONS OF STATE
    CHANG, T
    ROUSSEAU, RW
    KILPATRICK, PK
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1986, 25 (02): : 477 - 481
  • [8] Sorption enhanced steam reforming of ethanol on hydrotalcite-like compounds impregnated with active copper
    Cunha, A. F.
    Wu, Y. -J.
    Santos, J. C.
    Rodrigues, A. E.
    [J]. CHEMICAL ENGINEERING RESEARCH & DESIGN, 2013, 91 (03) : 581 - 592
  • [9] Steam reforming of ethanol on a Ni/Al2O3 catalyst coupled with a hydrotalcite-like sorbent in a multilayer pattern for co2 uptake
    Cunha, A. F.
    Wu, Y. J.
    Diaz Alvarado, Felipe A.
    Santos, J. C.
    Vaidya, P. D.
    Rodrigues, A. E.
    [J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2012, 90 (06) : 1514 - 1526
  • [10] How to Overcome the Water-Gas-Shift Equilibrium using a Conventional Nickel Reformer Catalyst
    Cunha, Adelino F.
    Moreira, Miguel N.
    Ribeiro, Ana Mafalda
    Ferreira, Alexandre P.
    Loureiro, Jose M.
    Rodrigues, Alirio E.
    [J]. ENERGY TECHNOLOGY, 2015, 3 (12) : 1205 - 1216
1234567