Synthesis of biomorphic Al2O3 based on natural plant templates and assembly of Ag nanoparticles controlled within the nanopores

被引：24

作者：

Fan, Tongxiang ^{[1
]}

Li, Xufan ^{[1
]}

Ding, Jian ^{[1
]}

Zhang, Di ^{[1
]}

Guo, Qixin ^{[2
]}

机构：

[1] Shanghai Jiao Tong Univ, State Key Lab Metal Matrix Composites, Shanghai 200030, Peoples R China

[2] Saga Univ, Dept Elect & Elect Engn, Saga 8408502, Japan

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2008年 / 108卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

biomorphic; template; nanopore; nanoparticles; SPR; NONLINEAR-OPTICAL RESPONSE; GOLD NANOPARTICLES; OXIDE CERAMICS; SURFACE-AREA; SILVER; REPLICATION; FABRICATION; COTTON; ROUTE;

D O I：

10.1016/j.micromeso.2007.03.050

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Biomorphic Al2O3 templated with charcoal and cotton is synthesized respectively and Ag nanopaticles are further assembled in the nanopores of biomorphic Al2O3. The morphology and pore structure of biomorphic Al2O3 as well as the size and properties of embedded Ag nanoparticles are characterized by FESEM, TEM, XRD, nitrogen adsorption and UV-vis. Biomorphic Al2O3 with two different templates show differences in the nanopore structure, and within the same template, the nanopore structure is also influenced by different synthesizing conditions. The size and distribution of further assembled Ag nanoparticles are in accordance with that of the nanopores of biomorphic Al2O3, and the intensity and position of surface plasma resonance (SPR) effect of Ag nanoparticles are influenced by their size and interaction with biomorphic Al2O3 matrixes. (c) 2007 Elsevier Inc. All rights reserved.

引用

页码：204 / 212

页数：9

共 46 条

[1]

Anderson MW, 2000, ANGEW CHEM INT EDIT, V39, P2707, DOI 10.1002/1521-3773(20000804)39:15<2707::AID-ANIE2707>3.0.CO

[2]

2-M

[3] Micrometer-to-manometer replication of hierarchical structures by using a surface sol-gel process [J].

Caruso, RA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (21) :2746-2748

[4] Sol-gel nanocoating: An approach to the preparation of structured materials [J].

Caruso, RA ;

Antonietti, M .

CHEMISTRY OF MATERIALS, 2001, 13 (10) :3272-3282

[5] Electron dynamics and surface plasmon resonance nonlinearities in metal nanoparticles [J].

Del Fatti, N ;

Vallée, F ;

Flytzanis, C ;

Hamanaka, Y ;

Nakamura, A .

CHEMICAL PHYSICS, 2000, 251 (1-3) :215-226

[6]

Dong AG, 2002, ADV MATER, V14, P926, DOI 10.1002/1521-4095(20020618)14:12<926::AID-ADMA926>3.0.CO

[7]

2-1

[8] Organization of metallic nanoparticles using tobacco mosaic virus templates [J].

Dujardin, E ;

Peet, C ;

Stubbs, G ;

Culver, JN ;

Mann, S .

NANO LETTERS, 2003, 3 (03) :413-417

[9] Nickel nanoparticles in silica gel: preparation and magnetic properties [J].

Estournes, C ;

Lutz, T ;

Happich, J ;

Quaranta, T ;

Wissler, P ;

Guille, JL .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1997, 173 (1-2) :83-92

[10] Microstructure and infrared absorption of biomorphic chromium oxides templated by wood tissues [J].

Fan, Tongxiang ;

Li, Xufan ;

Liu, Zhaoting ;

Gu, Jiajun ;

Zhang, Di ;

Guo, Qixin .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (11) :3511-3515

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