Magnesium hydridotriphenylborate [Mg(thf)6][HBPh3]2: a versatile hydroboration catalyst

被引：222

作者：

Mukherjee, Debabrata ^{[1
]}

Shirase, Satoru ^{[2
]}

Spaniol, Thomas P. ^{[1
]}

Mashima, Kazushi ^{[2
]}

Okuda, Jun ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Inorgan Chem, Landoltweg 1, D-52056 Aachen, Germany

[2] Osaka Univ, Grad Sch Engn Sci, Toyonaka, Osaka 5608531, Japan

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 89期

关键词：

SELECTIVE REDUCTION; CARBON-DIOXIDE; PYRIDINES; DEOXYGENATION; MOLYBDENUM; SULFOXIDES; COMPLEXES; REAGENTS; ESTERS; CO2;

D O I：

10.1039/c6cc06805g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Magnesium bis(hydridotriphenylborate), isolated as a solvent-separated ion pair [Mg(thf)(6)][HBPh3](2), effectively catalyzed the hydroboration of several unsaturated substrates including CO2.

引用

页码：13155 / 13158

页数：4

共 35 条

[1] Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center [J].

Abdalla, Joseph A. B. ;

Riddlestone, Ian M. ;

Tirfoin, Remi ;

Aldridge, Simon .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (17) :5098-5102

[2] Selective reduction of CO2 to a methanol equivalent by B(C6F5)3-activated alkaline earth catalysis [J].

Anker, Mathew D. ;

Arrowsmith, Merle ;

Bellham, Peter ;

Hill, Michael S. ;

Kociok-Koehn, Gabriele ;

Liptrot, David J. ;

Mahon, Mary F. ;

Weetman, Catherine .

CHEMICAL SCIENCE, 2014, 5 (07) :2826-2830

[3] Magnesium Catalysis of Imine Hydroboration [J].

Arrowsmith, Merle ;

Hill, Michael S. ;

Kociok-Koehn, Gabriele .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (08) :2776-2783

[4] Magnesium-catalysed hydroboration of aldehydes and ketones [J].

Arrowsmith, Merle ;

Hadlington, Terrance J. ;

Hill, Michael S. ;

Kociok-Koehn, Gabriele .

CHEMICAL COMMUNICATIONS, 2012, 48 (38) :4567-4569

[5] Magnesium-Catalyzed Hydroboration of Pyridines [J].

Arrowsmith, Merle ;

Hill, Michael S. ;

Hadlington, Terrance ;

Kociok-Koehn, Gabriele ;

Weetman, Catherine .

ORGANOMETALLICS, 2011, 30 (21) :5556-5559

[6]

Brown HC, 1996, ACS SYM SER, V641, P1

[7]

Chen G., 2005, SCI SYNTHESIS

[8] Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide [J].

Chong, Che Chang ;

Kinjo, Rei .

ACS CATALYSIS, 2015, 5 (06) :3238-3259

[9]

Dudnik AS, 2014, NAT CHEM, V6, P1100, DOI [10.1038/NCHEM.2087, 10.1038/nchem.2087]

[10] Deoxygenation of Sulfoxides to Sulfides in the Presence of Zinc Catalysts and Boranes as Reducing Reagents [J].

Enthaler, Stephan ;

Krackl, Sebastian ;

Irran, Elisabeth ;

Inoue, Shigeyoshi .

CATALYSIS LETTERS, 2012, 142 (08) :1003-1010

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