Effect of surface geometric structure on the adhesion force between silica particles

被引：34

作者：

Fuji, M ^{[1
]}

Machida, K ^{[1
]}

Takei, T ^{[1
]}

Watanabe, T ^{[1
]}

Chikazawa, M ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Dept Appl Chem, Grad Sch Engn, Tokyo 1920397, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1998年 / 102卷 / 44期

关键词：

D O I：

10.1021/jp981978+

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adhesion force between nonporous and porous silica particles was measured by AFM as a function of relative humidity. Various porous samples were prepared by hydrothermal treatments in different conditions. Geometric structure was evaluated by gas adsorption, and the mechanism of rehydroxylation that occurred in hydrothermal treatments was investigated by silanol density, IR spectra, and immersional heat, The adhesion force was measured by AFM, and the result was compared with the geometric structure and the rehydroxylation process. As a result, we proved that capillary condensation occurred in small spaces between two particles contacting each other after water filled the pores and capillary force appeared to contribute to a steep increase of adhesion force. The adhesion force under low relative pressure was attributed to hydrogen bending farce and reflected both the contact area and hydrophilicity of the surface.

引用

页码：8782 / 8787

页数：6

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