Oxidation-resistant ZrB2-SiC composites at 2200 °C

被引:295
作者
Han, Jiecai [1 ]
Hu, Ping [1 ]
Zhang, Xinghong [1 ]
Meng, Songhe [1 ]
Han, Wenbo [1 ]
机构
[1] Harbin Inst Technol, Ctr Composite Mat, Harbin 150001, Peoples R China
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
ultra-high-temperature ceramic (UHTC); ZrB2; SiC; oxidation resistance;
D O I
10.1016/j.compscitech.2007.08.017
中图分类号
TB33 [复合材料];
学科分类号
摘要
Oxidation resistance tests were carried out on hot-pressed Zi-B-2-20 vol%SiC using an oxyacetylene torch. The temperature of the oxidized specimens exceeded 2200 degrees C. The mass and linear oxidation rates of the ZrB2-20 vol%SiC composites for 10 min were -0.23 mg/s and 0.66 mu m/s, respectively. The surface layer appeared dense and adherent with the exception of a few burst bubbles and craterlets. No macro-cracks or spallation were detected after oxidation, suggesting that these composites possess a super oxidation resistance. The microstructure of the surface and cross-section of the oxidized specimens were studied by scanning electron microscopy along with energy dispersive spectrometry and X-ray diffraction. The oxidation mechanism was also discussed. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:799 / 806
页数:8
相关论文
共 16 条
  • [1] ALIREZA R, 2007, J EUR CERAM SOC, V27, P2495, DOI DOI 10.1016/J.JEURCERAMSOC.2006.10.012
  • [2] BUTTERMAN WC, 1967, AM MINERAL, V52, P880
  • [3] Chamberlain A, 2005, REFRACT APPL T, V1, P1
  • [4] Characterization of zirconium diboride for thermal protection systems
    Chamberlain, AL
    Fahrenholtz, WG
    Hilmas, GE
    Ellerby, DT
    [J]. EURO CERAMICS VIII, PTS 1-3, 2004, 264-268 : 493 - 496
  • [5] High-strength zirconium diboride-based ceramics
    Chamberlain, AL
    Fahrenholtz, WG
    Hilmas, GE
    Ellerby, DT
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2004, 87 (06) : 1170 - 1172
  • [6] Thermodynamic analysis of ZrB2-SiC oxidation:: Formation of a SiC-depleted region
    Fahrenholtz, William G.
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (01) : 143 - 148
  • [7] KOLODZIEJ P, 1997, 112204 NASA
  • [8] THE OXIDATION KINETICS OF ZIRCONIUM DIBORIDE AND ZIRCONIUM CARBIDE AT HIGH TEMPERATURES
    KURIAKOSE, AK
    MARGRAVE, JL
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1964, 111 (07) : 827 - 831
  • [9] Effect of ZrB2 on the ablation properties of carbon composites
    Li, XT
    Shi, JL
    Zhang, GB
    Zhang, H
    Guo, QG
    Liu, L
    [J]. MATERIALS LETTERS, 2006, 60 (07) : 892 - 896
  • [10] Loehman R, 2006, ULTRAHIGH TEMPERATUR, P1