energy transfer;
electron transfer;
catalysis;
photosystem II;
solar cells;
COUPLED ELECTRON-TRANSFER;
OXYGEN-EVOLVING CENTER;
WATER-OXIDATION CATALYSTS;
IRON-ONLY HYDROGENASE;
PHOTOSYSTEM-II;
ARTIFICIAL PHOTOSYNTHESIS;
REACTION CENTERS;
VISIBLE-LIGHT;
PHOTOASSISTED ELECTROLYSIS;
CHARGE RECOMBINATION;
D O I:
10.1146/annurev-conmatphys-062910-140503
中图分类号:
O469 [凝聚态物理学];
学科分类号:
070205 ;
摘要:
Solar energy has the capacity to fulfill global human energy demands in an environmentally and socially responsible manner, provided efficient, low-cost systems can be developed for its capture, conversion, and storage. Toward these ends, a molecular-based understanding of the fundamental principles and mechanistic details of energy conversion in photosynthesis is indispensable. This review addresses aspects of photosynthesis that may prove auspicious to emerging technologies. Conversely, areas in which human ingenuity may offer innovative solutions, resulting in enhanced energy storage efficiencies in artificial photosynthetic constructs, are considered. Emphasis is placed on photoelectrochemical systems that utilize water as a source of electrons for the production of solar fuels.
机构:
Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USAUniv Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
Jones, Anne K.
;
Lichtenstein, Bruce R.
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机构:Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
Lichtenstein, Bruce R.
;
Dutta, Arnab
论文数: 0引用数: 0
h-index: 0
机构:Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
Dutta, Arnab
;
Gordon, Gwyneth
论文数: 0引用数: 0
h-index: 0
机构:Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
Gordon, Gwyneth
;
Dutton, P. Leslie
论文数: 0引用数: 0
h-index: 0
机构:Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
机构:
Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USAUniv Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
Jones, Anne K.
;
Lichtenstein, Bruce R.
论文数: 0引用数: 0
h-index: 0
机构:Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
Lichtenstein, Bruce R.
;
Dutta, Arnab
论文数: 0引用数: 0
h-index: 0
机构:Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
Dutta, Arnab
;
Gordon, Gwyneth
论文数: 0引用数: 0
h-index: 0
机构:Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA
Gordon, Gwyneth
;
Dutton, P. Leslie
论文数: 0引用数: 0
h-index: 0
机构:Univ Penn, Sch Med, Johnson Res Fdn, Dept Biochem & Biophys, Philadelphia, PA 19104 USA