Novel phthalocyanines bearing 7-oxy-3-(3,5-difluorophenyl)coumarin moieties: Synthesis, characterization, photophysical and photochemical properties

被引：22
作者：
Erdogan, Tolga [1 ]
Bulut, Mustafa [1 ]
Camur, Meryem [2 ]
机构：
[1] Marmara Univ, Dept Chem, TR-34722 Istanbul, Turkey
[2] Kirklareli Univ, Dept Chem, TR-39100 Kirklareli, Turkey
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2015年 / 300卷
关键词：
Phthalocyanine; Coumarin; Zinc; Indium; Photodegradation; Singlet oxygen; PHOTODYNAMIC THERAPY; ZINC(II) PHTHALOCYANINE; INDIUM PHTHALOCYANINES; SUBSTITUTED GALLIUM; OPTICAL-PROPERTIES; COUMARIN; PHOTOSENSITIZERS; DERIVATIVES;
D O I：
10.1016/j.jphotochem.2014.12.005
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two novel phthalonitriles,7-(2,3-dicyanophenoxy)-3-(3,5-difluorophenyl) coumarin (2), 7-(3,4-dicyanophenoxy)-3-(3,5-difluorophenyl) coumarin (3), and corresponding zinc(II)-, indium(III) phthalocyanines were prepared. Additionally, photophysical (fluorescence quantum yields and lifetimes), photochemical (singlet oxygen generation and photodegradation under light irradiation) and spectral properties of the resulting peripherally/non-peripherally tetra 7-oxy-3-(3,5-difluorophenyl) coumarin substituted zinc (II) and indium (III) phthalocyanines (4-7) were investigated. All compounds (1-7) were characterized by elemental analysis, IR, H-1 NMR, mass and UV-vis spectral data. The obtained 7-oxy-3-(3,5-difluorophenyl) coumarin bearing pure zinc (II) and indium (III) phthalocyanine complexes were well soluble in organic solvents and displayed good singlet-oxygen generation and appropriate photodegradation. (C) 2014 Elsevier B.V. All rights reserved.
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页码：6 / 14
页数：9
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