Effect of commercial clays on the properties of SEBS/PP/oil thermoplastic elastomers. Part 1. Physical, mechanical and thermal properties

被引：21

作者：

Tiggemann, Hugo M. ^{[1
,2
]}

Ribeiro, Vanda F. ^{[3
]}

Celso, Fabricio ^{[4
]}

Nachtigall, Sonia M. B. ^{[1
]}

机构：

[1] Univ Fed Rio Grande do Sul, BR-91501970 Porto Alegre, RS, Brazil

[2] Integrated Reg Univ, Frederico Westphalen, RS, Brazil

[3] Softer Brasil Co, Campo Bom, RS, Brazil

[4] Feevale Univ, Novo Hamburgo, RS, Brazil

来源：

APPLIED CLAY SCIENCE | 2015年 / 109卷

关键词：

Flexible nanocomposites; Clay polymer nanocomposites (CPN); Mechanical properties; Thermal properties; Thermogravimetric analysis (TGA); TRIBLOCK COPOLYMER; POLYPROPYLENE; BLENDS; MORPHOLOGY; OIL;

D O I：

10.1016/j.clay.2015.02.028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thermoplastic elastomers based on SEBS/PP/oil blends show good flexibility at low temperatures, allowing complex shapes molding with good finishing. In this study, three different commercially available clays were used as fillers in these blends through melt mixing processes to produce clay polymer nanocomposites (CPN) with improved thermal and mechanical properties. The physicomechanical properties, melt flow index, density and thermal stability of the materials were studied. It was found that optimum concentration was 2 phr for all fillers. At this concentration, the mechanical properties reached a maximum while higher filler loading proved to be less beneficial. CPN prepared with Novaclay, a Brazilian clay organically modified with silane, showed the best properties, reaching 60% increase of mechanical resistance in comparison to the non-modified TPE matrix. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：151 / 156

页数：6

共 17 条

[1] Highly Transparent Thermoplastic Elastomer From Isotactic Polypropylene and Styrene/Ethylene-Butylene/Styrene Triblock Copolymer: Structure-Property Correlations [J].

Ahmad, Zubair ;

Kumar, K. Dinesh ;

Saroop, Madhumita ;

Preschilla, Nisha ;

Biswas, Amit ;

Bellare, Jayesh R. ;

Bhowmick, Anil K. .

POLYMER ENGINEERING AND SCIENCE, 2010, 50 (02) :331-341

[2]

Bergaya F, 2006, DEV CLAY SCI, V1, P1, DOI 10.1016/S1572-4352(05)01001-9

[3]

Brostow W., 2008, E-POLYMERS, V8, P355

[4] In vitro drug release from chitosan/Cloisite 15A hydrogels [J].

Cojocariu, Anca ;

Profire, Lenuta ;

Aflori, Magdalena ;

Vasile, Cornelia .

APPLIED CLAY SCIENCE, 2012, 57 :1-9

[5]

Deniz V., 2009, SOC PLAST ENG PLAST

[6] Mechanical and optical effects of elastomer interaction in polypropylene modification: Ethylene-propylene rubber, poly-(ethylene-co-octene) and styrene-butadiene elastomers [J].

Grein, C. ;

Gahleitner, M. ;

Bernreitner, K. .

EXPRESS POLYMER LETTERS, 2012, 6 (09) :688-696

[7]

Holden G., 1996, THERMOPLASTIC ELASTO, V2nd

[8] Mechanical properties of functionalized SEBS based inorganic hybrid materials [J].

Kausar, Ayesha ;

Zulfiqar, Sonia ;

Shabbir, Saima ;

Ishaq, Muhammad ;

Sarwar, Muhammad Ilyas .

POLYMER BULLETIN, 2007, 59 (04) :457-467

[9] Interfacial Interactions in PP/MMT/SEBS Nanocomposites [J].

Martin, Zulima ;

Jimenez, Ignacio ;

Angeles Gomez, M. ;

Ade, Harald ;

Kilcoyne, David A. .

MACROMOLECULES, 2010, 43 (01) :448-453

[10] Influence of compatibilizer degradation on formation and properties of PA6/organoclay nanocomposites [J].

Monticelli, Orietta ;

Musina, Zenfira ;

Frache, Alberto ;

Bellucci, Federica ;

Camino, Giovanni ;

Russo, Saverio .

POLYMER DEGRADATION AND STABILITY, 2007, 92 (03) :370-378

← 1 2 →