A zirconium hydrazide as a synthon for a metallanitrene equivalent:: atom-by-atom assembly of [EN2]2- units (E = S, Se) by chalcogen-atom transfer in the coordination sphere of a transition metal

被引：60

作者：

Herrmann, Heike ^{[1
]}

Fillol, Julio Lloret ^{[1
]}

Wadepohl, Hubert ^{[1
]}

Gade, Lutz H. ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 44期

关键词：

density functional calculations; hydrazides; nitrogen; X-ray diffraction; zirconium;

D O I：

10.1002/anie.200703938

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Piece by piece: Hydrazides at zirconium centers undergo facile N-N bond cleavage and react as equivalents for metallanitrenes, thus allowing the atom-by-atom assembly of bridging dinitridosulfate(IV) and dinitridoselenate(IV) ligands (see scheme; TBS = tBuMe2Si). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8426 / 8430

页数：5

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