A zirconium hydrazide as a synthon for a metallanitrene equivalent:: atom-by-atom assembly of [EN2]2- units (E = S, Se) by chalcogen-atom transfer in the coordination sphere of a transition metal

被引：60
作者：
Herrmann, Heike [1 ]
Fillol, Julio Lloret [1 ]
Wadepohl, Hubert [1 ]
Gade, Lutz H. [1 ]
机构：
[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 44期
关键词：
density functional calculations; hydrazides; nitrogen; X-ray diffraction; zirconium;
D O I：
10.1002/anie.200703938
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Piece by piece: Hydrazides at zirconium centers undergo facile N-N bond cleavage and react as equivalents for metallanitrenes, thus allowing the atom-by-atom assembly of bridging dinitridosulfate(IV) and dinitridoselenate(IV) ligands (see scheme; TBS = tBuMe2Si). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：8426 / 8430
页数：5
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