A zirconium hydrazide as a synthon for a metallanitrene equivalent:: atom-by-atom assembly of [EN2]2- units (E = S, Se) by chalcogen-atom transfer in the coordination sphere of a transition metal

被引：61

作者：

Herrmann, Heike ^{[1
]}

Fillol, Julio Lloret ^{[1
]}

Wadepohl, Hubert ^{[1
]}

Gade, Lutz H. ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 44期

关键词：

density functional calculations; hydrazides; nitrogen; X-ray diffraction; zirconium;

D O I：

10.1002/anie.200703938

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Piece by piece: Hydrazides at zirconium centers undergo facile N-N bond cleavage and react as equivalents for metallanitrenes, thus allowing the atom-by-atom assembly of bridging dinitridosulfate(IV) and dinitridoselenate(IV) ligands (see scheme; TBS = tBuMe2Si). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8426 / 8430

页数：5

共 79 条

[1] TiCl4/t-BuNH2 as the sole catalyst for a hydroamination-based Fischer indole synthesis [J].

Ackermann, L ;

Born, R .

TETRAHEDRON LETTERS, 2004, 45 (52) :9541-9544

[2] Syntheses and structures of selenido dimanganese and iron-manganese carbonyl cluster complexes [J].

Adams, RD ;

Kwon, OS ;

Sanyal, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 681 (1-2) :258-263

[3]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[4]

[Anonymous], Gaussian 03, Revision C.02 Gaussian, inc., wallingford, ct

[5] Titanium-catalyzed iminohydrazination of alkynes [J].

Banerjee, S ;

Shi, YH ;

Cao, CS ;

Odom, AL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (23) :5066-5077

[6] Synthesis and structure of a titanium hydrazido(2-) complex [J].

Banerjee, Sanjukta ;

Odom, Aaron L. .

ORGANOMETALLICS, 2006, 25 (13) :3099-2006

[7] Stepwise selenium transfer from tertiary phosphine selenides to [Ru3(CO)12].: Structural characterization of the primary product [(μ3-Se)(μ3-CO)(CO)7(PPh3)2] [J].

Belletti, D ;

Cauzzi, D ;

Graiff, C ;

Minarelli, A ;

Pattacini, R ;

Predieri, G ;

Tiripicchio, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (16) :3160-3163

[8]

Beurskens P. T., 1999, DIRDIF 99

[9] Group 4 imido complexes stabilized by a tridentate diamido-donor ligand [J].

Blake, AJ ;

Collier, PE ;

Gade, LH ;

Mountford, P ;

Lloyd, J ;

Pugh, SM ;

Schubart, M ;

Skinner, MEG ;

Trösch, DJM .

INORGANIC CHEMISTRY, 2001, 40 (05) :870-877

[10] Highly selective trimerisation of MeNC by a novel titanium imido complex containing a tridentate dianionic ligand [J].

Blake, AJ ;

Collier, PE ;

Gade, LH ;

McPartlin, M ;

Mountford, P ;

Schubart, M ;

Scowen, IJ .

CHEMICAL COMMUNICATIONS, 1997, (16) :1555-1556

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