Synthesis of Fe2O3/reduced graphene oxide composite anode materials with good cycle stability

被引:4
作者
Liu, Lilai [1 ]
Wu, Daqing [1 ]
Shao, Xiongchao [1 ]
Wang, Juan [1 ]
Nie, Jiahui [1 ]
Sun, Jiawen [1 ]
Wang, Sucheng [1 ]
机构
[1] Heilongjiang Univ Sci & Technol, Coll Environm & Chem Engn, Harbin, Peoples R China
关键词
Fe2O3; reduced graphene oxide; composite; anode; lithium-ion batteries; LITHIUM-ION BATTERIES; FE2O3/GRAPHENE COMPOSITE; RATE CAPABILITY; CARBON CLOTH; PERFORMANCE; STORAGE; NANOSHEETS; NANORODS; FE2O3;
D O I
10.1080/09276440.2016.1191834
中图分类号
TB33 [复合材料];
学科分类号
摘要
Fe2O3/reduced graphene oxide (Fe2O3/rGO) composite anode materials have been successfully synthesized by a polyvinylpyrrolidone (PVP)-assisted homogeneous precipitation method. The size of Fe2O3 nanoparticles on the surface of rGO sheets was less than 35nm. Fe2O3 nanoparticles and rGO sheets formed a network structure. Electrochemical properties were evaluated in two-electrode cells vs. metallic lithium. The Fe2O3/rGO composite exhibited excellent electrochemical lithium storage performances. The first discharge/charge capacities were 1600/1053mAh g(-1) at a current density of 100mAg(-1), and the coulomb efficiencies was 65.8%. The reversible specific capacity remained 893mAh g(-1) and the capacity retention was 84.8% after 100 cycles.
引用
收藏
页码:257 / 266
页数:10
相关论文
共 34 条
[1]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[2]   High power density nitridated hematite (α-Fe2O3) nanorods as anode for high-performance flexible lithium ion batteries [J].
Balogun, Muhammad-Sadeeq ;
Wu, Zupeng ;
Luo, Yang ;
Qiu, Weitao ;
Fan, Xiaolei ;
Long, Bei ;
Huang, Miao ;
Liu, Peng ;
Tong, Yexiang .
JOURNAL OF POWER SOURCES, 2016, 308 :7-17
[3]   Chemically Lithiated TiO2 Heterostructured Nanosheet Anode with Excellent Rate Capability and Long Cycle Life for High-Performance Lithium-Ion Batteries [J].
Balogun, Muhammad-Sadeeq ;
Zhu, Yikun ;
Qiu, Weitao ;
Luo, Yang ;
Huang, Yongchao ;
Liang, Chaolun ;
Lu, Xihong ;
Tong, Yexiang .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (46) :25991-26003
[4]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[5]   Enhanced rate capability of a lithium ion battery anode based on liquid-solid-solution assembly of Fe2O3 on crumpled graphene [J].
Cui, Xinghong ;
Zhu, Yanfang ;
Li, Fei ;
Liu, Daijun ;
Chen, Jianjun ;
Zhang, Yuxin ;
Zhang, Li Li ;
Ji, Junyi .
RSC ADVANCES, 2016, 6 (11) :9007-9012
[6]   Graphene: Status and Prospects [J].
Geim, A. K. .
SCIENCE, 2009, 324 (5934) :1530-1534
[7]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603
[8]   Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries [J].
Guo, Peng ;
Song, Huaihe ;
Chen, Xiaohong .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (06) :1320-1324
[9]   Electrochemical properties of nano-sized Fe2O3-loaded carbon as a lithium battery anode [J].
Hang, Bui Thi ;
Watanabe, Izumi ;
Doi, Takayuki ;
Okada, Shigeto ;
Yamaki, Jun-Ichi .
JOURNAL OF POWER SOURCES, 2006, 161 (02) :1281-1287
[10]   Prospective materials and applications for Li secondary batteries [J].
Jeong, Goojin ;
Kim, Young-Ugk ;
Kim, Hansu ;
Kim, Young-Jun ;
Sohn, Hun-Joon .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (06) :1986-2002