Color change of redox-active organometallic dithienylethene complexes by photochemical and redox processes

被引：7

作者：

Li, Huifang ^{[1
]}

Koike, Takashi ^{[1
]}

Akita, Munetaka ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

DYES AND PIGMENTS | 2012年 / 92卷 / 02期

关键词：

Dithienylethene; Photochromism; Redox reaction; Organo-iron complex; Organo-ruthenium complex; Mononuclear DTE complexes; PHOTOSWITCHABLE MOLECULAR WIRE; DIARYLETHENES; DTE; DERIVATIVES; RUTHENIUM; CHEMISTRY; BEHAVIOR;

D O I：

10.1016/j.dyepig.2011.03.029

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Photochromic dithienylethene (DTE) derivatives, DTE-MCpL2 {M = Fe, Ru: Cp = eta(5)-cyclopentadienyl; L-2 = (CO)(2), (CO)PPh3, dppe (dppe = Ph2PCH2CH2PPh2)}, with a directly sigma-bonded, redox-active organometallic attachment have been prepared and their response to photo- and electrochemical stimuli has been investigated. It turns out that the color of the organometallic derivatives can be controlled not only by photochromic processes but also by one-electron redox processes. The Ru complexes 1(Ru) and 2(Ru) exhibit reversible photochromism in a manner similar to organic DTE derivatives, with ring closing and ring opening triggered by UV and visible-light irradiation, respectively. Their photochromic behavior is critically dependent on both of the central metal and ligands. One-electron oxidation of the Fe complex 3(Fe) gives the corresponding radical cationic species with a visible absorption. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：854 / 860

页数：7

共 50 条

[21] Multistate Redox-Active Metalated Triarylamines [J].

Grelaud, Guillaume ;

Cifuentes, Marie P. ;

Schwich, Torsten ;

Argouarch, Gilles ;

Petrie, Simon ;

Stranger, Rob ;

Paul, Frederic ;

Humphrey, Mark G. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (01) :65-75

[22] Redox-active electrolyte for supercapacitor application [J].

Frackowiak, Elzbieta ;

Meller, Mikolaj ;

Menzel, Jakub ;

Gastol, Dominika ;

Fic, Krzysztof .

FARADAY DISCUSSIONS, 2014, 172 :179-198

[23] Iodophenylsulfonates and Iodobenzoates as Redox-Active Supporting Electrolytes for Electrosynthesis [J].

Roesel, Arend F. ;

Broese, Timo ;

Majek, Michal ;

Francke, Robert .

CHEMELECTROCHEM, 2019, 6 (16) :4229-4237

[24] Titanium thiosalicylate complexes: functional metalloligands for the construction of redox-active heterometallic architectures [J].

Fandos, Rosa ;

Bruna, Sonia ;

Hernandez, Carolina ;

Otero, Antonio ;

Rodriguez, Ana ;

Ruiz, Maria Jose ;

Terreros, Pilar ;

Cuadrado, Isabel .

DALTON TRANSACTIONS, 2018, 47 (43) :15391-15398

[25] Coordination polymers derived from alkali metal complexes of redox-active ligands [J].

Bazyakina, Natalia L. ;

Moskalev, Mikhail, V ;

Cherkasov, Anton, V ;

Makarov, Valentin M. ;

Fedushkin, Igor L. .

CRYSTENGCOMM, 2022, 24 (12) :2297-2304

[26] Europium(III) DOTA-tetraamide Complexes as Redox-Active MRI Sensors [J].

Ratnakar, S. James ;

Viswanathan, Subha ;

Kovacs, Zoltan ;

Jindal, Ashish K. ;

Green, Kayla N. ;

Sherry, A. Dean .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (13) :5798-5800

[27] Dinuclear Nickel Complexes in Five States of Oxidation Using a Redox-Active Ligand [J].

Zhou, You-Yun ;

Hartline, Douglas R. ;

Steiman, Talia J. ;

Fanwick, Phillip E. ;

Uyeda, Christopher .

INORGANIC CHEMISTRY, 2014, 53 (21) :11770-11777

[28] Elucidating the Correlation Between the Redox Potential, Spin State, and Crystal Structure in a Series of Ferrous Complexes with Redox-Active Ligands [J].

Getzner, Livia ;

Remili, Yasmine ;

Ziani, Zakaria ;

Vendier, Laure ;

Nicolazzi, William ;

Rotaru, Aurelian ;

Yu, Haizhu ;

Molnar, Gabor ;

Cobo, Saioa ;

Bousseksou, Azzedine .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025,

[29] Redox-Active Heteroatom-Functionalized Polyacetylenes [J].

Luppi, Bruno T. ;

Muralidharan, Abhishek, V ;

Ostermann, Nils ;

Cheong, I. T. ;

Ferguson, Michael J. ;

Siewert, Inke ;

Rivard, Eric .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (04)

[30] Incorporating sulfur into redox-active reagents and materials [J].

Beil, Sebastian B. ;

Wonink, Marco B. S. ;

Feringa, Ben L. .

TETRAHEDRON, 2023, 132

← 1 2 3 4 5 →