Synthesis and structure of the chromiumcarbonyl complexed phenyl allene

被引：5

作者：

Ansorge, M ^{[1
]}

Polborn, K ^{[1
]}

Müller, TJJ ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 630卷 / 02期

关键词：

addition; allenes; arene complexes; chromium; structure;

D O I：

10.1016/S0022-328X(01)00867-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chromiumtricarbonyl complexed phenyl allene 4 can be readily synthesized by palladium catalyzed hydride reduction or dimethyl cuprate mediated reduction of suitable propargyl ester derivatives 3 and 5. This parent compound of chromiumcarbonyl complexed aryl allenes is fairly stable and is unambiguously characterized by an X-ray structure analysis. Thiolate adds to 4 to give a 3.5:1 distribution between the nonconjugated and the conjugated addition products 7 and 8 in good yield. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：198 / 204

页数：7

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