Reduction of Tb4+ ions in luminescent Y2O3: Tb nanorods prepared by microwave hydrothermal method

被引：43

作者：

Kaszewski, Jaroslaw ^{[1
]}

Witkowski, Bartlomiej S. ^{[1
]}

Wachnicki, Lukasz ^{[1
]}

Przybylinska, Hanka ^{[1
]}

Kozankiewicz, Boleslaw ^{[1
]}

Mijowska, Ewa ^{[2
]}

Godlewski, Marek ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Phys, Al Lotnikow 32-46, PL-02668 Warsaw, Poland

[2] West Pomeranian Univ Technol, Inst Chem & Environm Engn, Ul Pulaskiego 10, PL-70322 Szczecin, Poland

来源：

JOURNAL OF RARE EARTHS | 2016年 / 34卷 / 08期

关键词：

yttrium oxide; terbium; luminescence; biomarkers; abnormal reduction; rare earths; EFFICIENCY; SILICA; ZIRCON; IMPACT; GREEN; SIZE; EPR;

D O I：

10.1016/S1002-0721(16)60093-5

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Terbium doped yttrium oxide was prepared with the microwave hydrothermal method. The Y2O3: Tb nanomaterial crystallized as needle-like grains. Bright luminescence in the green region was observed. Significant luminescence intensity increase was obtained after thermal treatment. Reduction of terbium ions was observed after heating in the air atmosphere. Tb4+ ions were found to be stabilized by crystal impurities. Hydroxyl species were found to have impact on vacancies elimination. The terbium ions were used as optical and magnetic indicator of the material properties.

引用

页码：774 / 781

页数：8

共 31 条

[11] Controlling the morphology of yttrium oxide through different precursors synthesized by hydrothermal method [J].

Li, Nan ;

Yanagisawa, Kazumichi .

JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (08) :1738-1743

[12]

Lojkowski W, MICROWAVE DRIVEN HYD

[13]

Misra S. N., 1994, Proc.-Indian Natl. Sci. Acad. Part A, Phys. Sci., V60, P637

[14] Effect of structure, particle size and relative concentration of Eu3+ and Tb3+ ions on the luminescence properties of Eu3+ co-doped Y2O3: Tb nanoparticles [J].

Mukherjee, S. ;

Sudarsan, V. ;

Vatsa, R. K. ;

Godbole, S. V. ;

Kadam, R. M. ;

Bhatta, U. M. ;

Tyagi, A. K. .

NANOTECHNOLOGY, 2008, 19 (32)

[15] THE VALENCE CHANGE FROM RE3+ TO RE2+ (RE-EQUIVALENT-TO-EU, SM, YB) IN SRB4O7-RE PREPARED IN AIR AND THE SPECTRAL PROPERTIES OF RE2+ [J].

PEI, ZW ;

SU, Q ;

ZHANG, JY .

JOURNAL OF ALLOYS AND COMPOUNDS, 1993, 198 (1-2) :51-53

[16] Photoluminescence properties of nanocrystalline Tb3+ doped Y2O3 phosphor prepared through a novel synthetic route [J].

Ray, S. ;

Patra, A. ;

Pramanik, P. .

OPTICAL MATERIALS, 2007, 30 (04) :608-616

[17] Rare earth phosphors: fundamentals and applications [J].

Ronda, CR ;

Justel, T ;

Nikol, H .

JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 275 :669-676

[18] A comparative investigation on ion impact parameters and TL response of Y2O3:Tb3+ nanophosphor exposed to swift heavy ions for space dosimetry [J].

Som, S. ;

Dutta, S. ;

Chowdhury, M. ;

Kumar, Vijay ;

Kumar, Vinod ;

Swart, H. C. ;

Sharma, S. K. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 589 :5-18

[19] Hydrothermal zirconia powders: A bibliography [J].

Somiya, S ;

Akiba, T .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (01) :81-87

[20] Dependence of photoluminescent properties of cubic Y2O3:Tb3+ nanocrystals on particle size and temperature [J].

Song, HW ;

Wang, JW .

JOURNAL OF LUMINESCENCE, 2006, 118 (02) :220-226

← 1 2 3 4 →