Low-cost chemiresistive sensor for volatile amines based on a 2D network of a zinc(II) Schiff-base complex

被引:28
作者
Mirabella, S. [1 ,2 ]
Oliveri, I. P. [3 ]
Ruffino, F. [1 ,2 ]
Maccarrone, G. [3 ]
Di Bella, S. [3 ]
机构
[1] Univ Catania, CNR, MATIS IMM, Via S Sofia 64, I-95123 Catania, Italy
[2] Univ Catania, Dipartimento Fis & Astron, Via S Sofia 64, I-95123 Catania, Italy
[3] Univ Catania, Dipartimento Sci Chim, Viale A Doria 6, I-95125 Catania, Italy
关键词
COMPOSITE VAPOR DETECTORS; ORGANIC-COMPOUNDS; LEWIS BASICITY; FISH SPOILAGE; GAS SENSOR; ARRAYS; SENSITIVITY; SELECTIVITY;
D O I
10.1063/1.4963790
中图分类号
O59 [应用物理学];
学科分类号
摘要
A marked chemiresistive behavior is revealed in a nanostructured material obtained by spin-coating a solution of a bis(salycilaldiminato) Zn(II) Schiff-base (ZnSB) complex. The resulting submicron 2D network exhibits reversible changes in absorbance and resistance under the cycles of absorption and desorption of a volatile amine. These results are explained in terms of a Lewis donor-acceptor interaction between the ZnSB (acceptor) and the chemisorbed amine (donor). The 2D network of ZnSB was employed as a sensing element to fabricate a low-cost device for the volatile amines detection, showing promising results for food spoilage detection. Published by AIP Publishing.
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页数:4
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