Light Emission from Nanocrystalline Si Inverse Opals and Controlled Passivation by Atomic Layer Deposited Al2O3

被引:14
作者
Gallego-Gomez, Francisco [1 ,2 ]
Ibisate, Marta [1 ,2 ]
Golmayo, Dolores [1 ,2 ]
Palomares, F. Javier [1 ,2 ]
Herrera, Miriam [3 ]
Hernandez, Jesus [3 ]
Molina, Sergio I. [3 ]
Blanco, Alvaro [1 ,2 ]
Lopez, Cefe [1 ,2 ]
机构
[1] CSIC U Vigo, Consejo Super Invest Cient, Inst Ciencia Mat Madrid, Madrid 28049, Spain
[2] CSIC U Vigo, Consejo Super Invest Cient, Unidad Asociada, Madrid 28049, Spain
[3] Univ Cadiz, Dept Ciencia Mat & Ingn Met & Quim Inorgan, Fac Ciencias, Cadiz 11510, Spain
关键词
SILICON NANOCRYSTALS; POROUS SILICON; PHOTOLUMINESCENCE; LUMINESCENCE; FILMS; NANOPARTICLES; ASSEMBLIES; REDUCTION;
D O I
10.1002/adma.201101797
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
3D-nanostructured ensembles of silicon nanocrystals forming inverse opals, directly prepared by magnesioreduction, exhibited intense photoluminescence in a broadband range (visible and NIR). Light emission, which strongly diminished under photoexcitation, was preserved by engineering the nanocrystals interface with atomic layer deposition of alumina. The high accessibility of the nanocrystals throughout the self-supported structure was a key factor for efficient photoluminescence stabilization. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5219 / 5223
页数:5
相关论文
共 27 条
  • [1] Chemical reduction of three-dimensional silica micro-assemblies into microporous silicon replicas
    Bao, Zhihao
    Weatherspoon, Michael R.
    Shian, Samuel
    Cai, Ye
    Graham, Phillip D.
    Allan, Shawn M.
    Ahmad, Gul
    Dickerson, Matthew B.
    Church, Benjamin C.
    Kang, Zhitao
    Abernathy, Harry W., III
    Summers, Christopher J.
    Liu, Meilin
    Sandhage, Kenneth H.
    [J]. NATURE, 2007, 446 (7132) : 172 - 175
  • [2] Large-scale synthesis of a silicon photonic crystal with a complete three-dimensional bandgap near 1.5 micrometres
    Blanco, A
    Chomski, E
    Grabtchak, S
    Ibisate, M
    John, S
    Leonard, SW
    Lopez, C
    Meseguer, F
    Miguez, H
    Mondia, JP
    Ozin, GA
    Toader, O
    van Driel, HM
    [J]. NATURE, 2000, 405 (6785) : 437 - 440
  • [3] Silicon onion-layer nanostructures arranged in three dimensions
    Blanco, Alvaro
    Lopez, Cefe
    [J]. ADVANCED MATERIALS, 2006, 18 (12) : 1593 - +
  • [4] Three-dimensional magnesia-based nanocrystal assemblies via low-temperature magnesiothermic reaction of diatom microshells
    Cai, Y
    Allan, SM
    Sandhage, KH
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (07) : 2005 - 2010
  • [5] Emission intermittency in silicon nanocrystals
    Cichos, F
    Martin, J
    von Borczyskowski, C
    [J]. PHYSICAL REVIEW B, 2004, 70 (11) : 115314 - 1
  • [6] Spin-on nanostructured silicon-silica film displaying room-temperature nanosecond lifetime photoluminescence
    Cohen, Y
    Hatton, B
    Míguez, H
    Coombs, N
    Fournier-Bidoz, SB
    Grey, JK
    Beaulac, R
    Reber, C
    Ozin, GA
    [J]. ADVANCED MATERIALS, 2003, 15 (7-8) : 572 - 576
  • [7] The structural and luminescence properties of porous silicon
    Cullis, AG
    Canham, LT
    Calcott, PDJ
    [J]. JOURNAL OF APPLIED PHYSICS, 1997, 82 (03) : 909 - 965
  • [8] Nanosilicon photonics
    Daldosso, Nicola
    Pavesi, Lorenzo
    [J]. LASER & PHOTONICS REVIEWS, 2009, 3 (06) : 508 - 534
  • [9] de Boer WDAM, 2010, NAT NANOTECHNOL, V5, P878, DOI [10.1038/nnano.2010.236, 10.1038/NNANO.2010.236]
  • [10] Classification and control of the origin of photoluminescence from Si nanocrystals
    Godefroo, S.
    Hayne, M.
    Jivanescu, M.
    Stesmans, A.
    Zacharias, M.
    Lebedev, O. I.
    Van Tendeloo, G.
    Moshchalkov, V. V.
    [J]. NATURE NANOTECHNOLOGY, 2008, 3 (03) : 174 - 178