Fischer-Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al))

被引：42

作者：

Isaeva, V. I. ^{[1
]}

Eliseev, O. L. ^{[1
]}

Kazantsev, R. V. ^{[1
]}

Chernyshev, V. V. ^{[2
,4
]}

Davydov, P. E. ^{[1
]}

Saifutdinov, B. R. ^{[3
]}

Lapidus, A. L. ^{[1
]}

Kustov, L. M. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Leninsky Prospect 47, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Leninskie Gory 1,Bldg 3, Moscow 119992, Russia

[3] Samara State Tech Univ, Molodogvardeiskaya Ul 244, Samara 443100, Russia

[4] AN Frumkin Inst Phys Chem & Electrochem RAS, 31 Leninsky Prospect, Moscow 119071, Russia

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 30期

基金：

俄罗斯科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; CO HYDROGENATION ACTIVITY; NANOPARTICLES; CARBON; REDUCIBILITY; ADSORPTION; STABILITY; MIL-53; AL2O3; SIZE;

D O I：

10.1039/c6dt01394e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel nanohybrid materials were prepared by immobilizing Co nanoparticles on a microporous framework MIL-53(Al) as a porous host matrix. The synthesized cobalt-containing materials were characterized by XRD, STEM, and oxygen titration. The catalytic performance of Co@MIL-53(Al) nanohybrids was examined in Fischer-Tropsch synthesis (FTS) for the first time. A higher selectivity to C5+ hydrocarbons and lower selectivity to methane for Co@MIL-53(Al) as compared to conventional Co/Al2O3 were observed.

引用

页码：12006 / 12014

页数：9

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