Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals

被引：8
|
作者：
Angeloski, Alexander [1 ]
Cortie, Michael B. [1 ]
Scott, John A. [1 ]
Bordin, Dayanne M. [1 ]
McDonagh, Andrew M. [1 ]
机构：
[1] Univ Technol Sydney, Sch Math & Phys Sci, Ultimo 2007, Australia
来源：
INORGANICA CHIMICA ACTA | 2019年 / 487卷
关键词：
Dithiocarbamate; Nickel; Thermolysis; HIGH-PERFORMANCE SUPERCAPACITORS; THIN-FILMS; ELECTROCHEMICAL PERFORMANCE; COUNTER ELECTRODES; VAPOR-DEPOSITION; HOLLOW SPHERES; BETA-NIS; PHASE; NANOPARTICLES; COMPOSITES;
D O I：
10.1016/j.ica.2018.12.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of bis(kappa S-2,S'-di(isopropyl)dithiocarbamato) nickel(II) were utilized as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at - 250 degrees C to form alpha-NiS exclusively with no beta-NiS detected. Analysis of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and carbon disulfide. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relationships.
引用
收藏
页码：228 / 233
页数：6
相关论文
共 50 条
  • [41] Determination of nickel(II) as the nickel dimethylglyoxime complex using colorimetric solid phase extraction
    Gazda, DB
    Fritz, JS
    Porter, MD
    ANALYTICA CHIMICA ACTA, 2004, 508 (01) : 53 - 59
  • [42] FLOATING-ZONE GROWTH AND OPTICAL-PROPERTIES OF NICKEL TANTALUM OXIDE SINGLE-CRYSTALS
    ANDO, K
    HIGUCHI, M
    TAKAHASHI, J
    KODAIRA, K
    MATERIALS RESEARCH BULLETIN, 1994, 29 (04) : 385 - 391
  • [43] Synthesis, properties, and reactions of trinuclear macrocyclic nickel(II) and nickel(I) complexes:: Electrocatalytic reduction of CO2 by nickel(II) complex
    Lee, EY
    Hong, DW
    Park, HW
    Suh, MP
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (17) : 3242 - 3249
  • [44] Enantiomorph conversion in single crystals of the Weyl semimetal CoSi
    Carrillo-Cabrera, Wilder
    Simon, Paul
    Schmidt, Marcus
    Koenig, Markus
    Borrmann, Horst
    Winkelmann, Aimo
    Burkhardt, Ulrich
    Grin, Yuri
    COMMUNICATIONS MATERIALS, 2023, 4 (01)
  • [45] Preparation of Nickel Sulfide Thin Films and Nanocrystallites Using Nickel Furfuraldehyde Thiosemicarbazone as Single-source Precursor
    Gole, Ajay V.
    Garje, Shivram S.
    MANUFACTURING SCIENCE AND TECHNOLOGY, PTS 1-8, 2012, 383-390 : 3828 - 3834
  • [46] Enhancement of second harmonic generation efficiency: Growth and characterization of magnesium(II)-doped tetrakis(thiourea)nickel(II) chloride crystals
    Muthu, K.
    Mahadevan, C. K.
    Meenakshisundaram, S. P.
    OPTIK, 2014, 125 (01): : 50 - 54
  • [47] Conversion of imine ligands in allyl-nickel(II) complexes
    Kraikivskii, Peter B.
    Klein, Hans-Friedrich
    Saraev, Vitaly V.
    Meusinger, Reinhard
    Svoboda, Ingrid
    Pashchanka, Mikhail
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (24) : 3912 - 3917
  • [48] Synthesis and crystal structure of a zwitterionic nickel(II) complex
    Dinsmore, A
    Ikhide, P
    Billing, DG
    Fernandes, MA
    Marsicano, F
    Selemela, L
    INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (03) : 293 - 296
  • [49] Electrocatalytic and photocatalytic activity of a nickel (II) quinacridone complex
    Mousavi, Negin
    Hadadzadeh, Hassan
    Ensafi, Ali A.
    Farrokhpour, Hossein
    Mousaabadi, Kimia Zarean
    MATERIALS CHEMISTRY AND PHYSICS, 2023, 303
  • [50] EFFECTS OF SPALLATION NEUTRON-IRRADIATION ON SINGLE-CRYSTALS OF IRON, NICKEL, NIOBIUM AND STAINLESS-STEEL
    GUPTA, S
    MESSOLORAS, S
    STEWART, RJ
    WILSON, CC
    BROWN, RD
    BRADBURY, J
    RADIATION EFFECTS AND DEFECTS IN SOLIDS, 1991, 116 (04): : 299 - 306
12345