1,2-Bis(2-pyridylformimidoyl)hydrazine

被引:15
|
作者
Armstrong, JA
Barnes, JC
Weakley, TJR
机构
[1] Univ Dundee, Dept Chem, Dundee DD1 4HN, Scotland
[2] Univ Oregon, Dept Chem, Eugene, OR 97403 USA
关键词
D O I
10.1107/S0108270198008014
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C12H12N6, is the minor trans product of the preparation of a dihydrotetrazine. Extensive electron delocalization is shown by the planarity of the molecule, except for one pyridyl group twisted out of plane by 14.1(1)degrees. The C=N-N=C fragment has a C-N distance of 1.297(2)Angstrom and an N-N distance of 1.404(2)A. All other C-N distances are close to 1.34 Angstrom, typical of C=N bonds. The NH2 groups form hydrogen bonds to pyridyl and hydrazine N atoms of adjacent molecules.
引用
收藏
页码:1923 / 1925
页数:3
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