New Roles for Photoexcited Eosin Y in Photochemical Reactions

被引:154
作者
Yan, Dong-Mei [1 ]
Chen, Jia-Rong [1 ]
Xiao, Wen-Jing [1 ]
机构
[1] Cent China Normal Univ, Key Lab Pesticides & Chem Biol, CCNU UOttawa Joint Res Ctr, Minist Educ,Coll Chem, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China
关键词
C-H functionalization; eosin Y; hydrogen atom transfer; photoacids; photoredox catalysis; VISIBLE-LIGHT PHOTOREDOX; HYDROGEN-ATOM TRANSFER; CATALYSIS;
D O I
10.1002/anie.201811102
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Neutral eosin Y-derived photoexcited states have been found to serve as photoacids and direct hydrogen atom transfer (HAT) catalysts in the activation of glycals and C-H bonds, respectively. These studies pave the way for further use of eosin Y in photochemical synthesis.
引用
收藏
页码:378 / 380
页数:3
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