Enantioselective Henry reaction catalyzed by trianglamine-Cu(OAC)2 complex under solvent-free conditions

被引：45
|
作者：
Tanaka, Koichi [1 ]
Hachiken, Satoshi
机构：
[1] Kansai Univ, Dept Chem & Mat Engn, Fac Chem Mat & Bioengn, Osaka 5648680, Japan
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 16期
关键词：
D O I：
10.1016/j.tetlet.2008.02.113
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral trianglamine-Cu(OAc)(2) complex was found to be an efficient catalyst for enantioselective Henry reaction between nitromethane and various aldehydes to provide beta-hydroxynitoroalkanes with high enantiomeric excesses under solvent-free conditions. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2533 / 2536
页数：4
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