Asymmetric allylation of aromatic aldehydes using chiral allylic tin reagents

被引：17
|
作者：
Nishida, M
Tozawa, T
Yamada, K
Mukaiyama, T
机构：
[1] Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, Tokyo 162, Kagurazaka, Shinjuku-ku
来源：
CHEMISTRY LETTERS | 1996年 / 12期
关键词：
D O I：
10.1246/cl.1996.1125
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chiral allylating reagents, readily generated in situ from 2 lambda(2)-1,3,2-benzodioxastannole [Sn-II(O2C6H4)], allyl halides, chiral dialkyl tartrates and 1,8-diazabicyclo[5.4.0]-7-undecene (DBU) smoothly react with aromatic aldehydes at -78 degrees C in the presence of a catalytic amount of copper salts to afford the corresponding homoallylic alcohols in high yields with high enantioselectivities.
引用
收藏
页码：1125 / 1126
页数：2
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