Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N,N′)-(thiodiacetato-κ3O,S,O′)cobalt(II) dihydrate

被引：6
|
作者：
Liu, BX [1 ]
Yu, JY
Xu, DJ
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou, Peoples R China
[2] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536805028059
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title Co-II complex, [Co(C6H6N4S2)(C4H4O4S)(H2O)]-2H(2)O, assumes a distorted octahedral coordination geometry formed by a diaminobithiazole (DABT) ligand, a thio-diacetate dianion (TDA) and a water molecule. The TDA dianion chelates to the Co-II atom with a facial configuration. Within the chelating DABT ligand, the two thiazole rings are twisted with respect to each other [ dihedral angle = 12.04 (9)degrees].
引用
收藏
页码：M1978 / M1980
页数：3
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