Synthesis of 3-Aroylpyrrolo[1,2-a][4,1]benzoxazepine-1,2,4(6H)-triones by the Reaction of 2-(2-Aryl-2-oxoethylidene)-1,5-dihydro-4,1-benzoxazepin-3(2H)-ones with Oxalyl Chloride

被引:0
作者
Maslivets, A. A. [1 ]
Dmitriev, M., V [1 ]
Maslivets, A. N. [1 ]
机构
[1] Perm State Univ, Perm 614990, Russia
基金
俄罗斯科学基金会;
关键词
enamino ketones; 2-methylidenebenzoxazepin-3-ones; pyrrolobenzoxazepinetriones; hetareno[e]-pyrrole-2; 3-diones; X-ray analysis; TRANSFORMATIONS; ANNULATION;
D O I
10.1134/S1070428021100067
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The condensation of aroylpyruvic acids with o-aminobenzyl alcohol gave (Z)-2-(2-aryl-2-oxo-ethylidene)-1,5-dihydro-4,1-benzoxazepin-3(2H)-ones which reacted with oxalyl chloride to afford 3-aroylpyr-rolo-[1,2-a][4,1]benzoxazepine-1,2,4(6H)-triones.
引用
收藏
页码:1608 / 1613
页数:6
相关论文
共 24 条
  • [1] Interaction of 3-ethoxycarbonylmethylene-1,2,3,4-tetrahydro-2-quinoxalone with oxalyl chloride. Synthesis and crystal and molecular structure of 4-ethoxycarbonyl-3,5-dihydro-2H-pyrano[2,3-b]quinoxaline-2,3-dione
    Aliev, ZG
    Maslivets, AN
    Golovnina, OV
    Krasnykh, OP
    Atovmyan, LO
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 43 (03) : 535 - 538
  • [2] [Anonymous], 2010, Agilent Technologies
  • [3] Synthesis of reactive γ-lactams related to penicillins and cephalosporins
    Bhattia, SH
    Davies, GM
    Hitchcock, PB
    Loakes, D
    Young, DW
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (17): : 2449 - 2454
  • [4] Five-membered 2,3-dioxo heterocycles:: L.: Synthesis and thermolysis of 3-aroyl- and 3-hetaroyl-5-phenyl-1,2,4,5-tetrahydropyrrolo[1,2-a]quinoxalin-1,2,4-triones
    Bozdyreva, KS
    Smirnova, IV
    Maslivets, AN
    [J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 41 (07) : 1081 - 1088
  • [5] Annulation of heterocyclic secondary enamines with dicarboxylic acid dichlorides, an unexpected ring size effect
    Cheng, Y
    Yang, HB
    Huang, ZT
    Wang, MX
    [J]. TETRAHEDRON LETTERS, 2001, 42 (09) : 1757 - 1759
  • [6] Synthesis of pyrrolo[1,2-a]pyrazine-1,6,7-triones from 3-methylidenepiperazin-2-ones and oxalyl chloride
    Chervyakov, A. V.
    Maslivets, A. N.
    [J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 49 (06) : 943 - 944
  • [7] The unusual thermal transformations of the dimethyl 2,2,3,3-tetramethyl-7a-R-1,2,3,7a-tetrahydroimidazo[1,2-b]isoxazole-6,7-dicarboxylate derivatives
    Chukanov, Nikita V.
    Popov, Sergey A.
    Romanenko, Galina V.
    Reznikov, Vladimir A.
    [J]. TETRAHEDRON, 2008, 64 (30-31) : 7432 - 7436
  • [8] OLEX2: a complete structure solution, refinement and analysis program
    Dolomanov, Oleg V.
    Bourhis, Luc J.
    Gildea, Richard J.
    Howard, Judith A. K.
    Puschmann, Horst
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 : 339 - 341
  • [9] Synthesis of ene-1,1-diamines and pyrrolo[1,2-a]imidazolediones by 4,5-dihydroimidazole N-oxide cycloaddition and isoxazoline ring opening
    Jones, RCF
    Martin, JN
    Smith, P
    Gelbrich, T
    Light, ME
    Hursthouse, MB
    [J]. CHEMICAL COMMUNICATIONS, 2000, (19) : 1949 - 1950
  • [10] Annulation of imidazolines with bis-electrophiles: Synthesis of imidazo[1,2-a]pyridines
    Jones, RCF
    Patel, P
    Hirst, SC
    Smallridge, MJ
    [J]. TETRAHEDRON, 1998, 54 (22) : 6191 - 6200