Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR

被引：398

作者：

Thankamony, Aany Sofia Lilly

Wittmann, Johannes J.

Kaushik, Monu

Corzilius, Bjoern ^{[1
]}

机构：

[1] Goethe Univ Frankfurt, Inst Phys & Theoret Chem, Inst Biophys Chem, Max von Laue Str 7-9, D-60438 Frankfurt, Germany

来源：

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY | 2017年 / 102卷

关键词：

ELECTRON-PARAMAGNETIC-RESONANCE; C-13-C-13 CORRELATION SPECTROSCOPY; NATURAL ISOTOPIC ABUNDANCE; SPIN-LATTICE-RELAXATION; 250 GHZ GYROTRON; MESOPOROUS SILICA NANOPARTICLES; ATOMIC-RESOLUTION STRUCTURE; BROADENED ESR LINE; MAGNETIC-RESONANCE; C-13; NMR;

D O I：

10.1016/j.pnmrs.2017.06.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The field of dynamic nuclear polarization has undergone tremendous developments and diversification since its inception more than 6 decades ago. In this review we provide an in-depth overview of the relevant topics involved in DNP-enhanced MAS NMR spectroscopy. This includes the theoretical description of DNP mechanisms as well as of the polarization transfer pathways that can lead to a uniform or selective spreading of polarization between nuclear spins. Furthermore, we cover historical and state-of-the art aspects of dedicated instrumentation, polarizing agents, and optimization techniques for efficient MAS DNP. Finally, we present an extensive overview on applications in the fields of structural biology and materials science, which underlines that MAS DNP has moved far beyond the proof-of-concept stage and has become an important tool for research in these fields. (C) 2017 The Authors. Published by Elsevier B.V.

引用

页码：120 / 195

页数：76

共 478 条

[11] MOLECULAR-DYNAMICS OF POLYCARBONATE CHAINS AT THE INTERFACE OF POLYCARBONATE POLYSTYRENE HETEROGENEOUS BLENDS [J].

AFEWORKI, M ;

SCHAEFER, J .

MACROMOLECULES, 1992, 25 (16) :4097-4099

[12] SELECTIVE OBSERVATION OF THE INTERFACE OF HETEROGENEOUS POLYCARBONATE POLYSTYRENE BLENDS BY DYNAMIC NUCLEAR-POLARIZATION C-13 NMR-SPECTROSCOPY [J].

AFEWORKI, M ;

MCKAY, RA ;

SCHAEFER, J .

MACROMOLECULES, 1992, 25 (16) :4084-4091

[13] De Novo 3D Structure Determination from Sub-milligram Protein Samples by Solid-State 100 kHz MAS NMR Spectroscopy [J].

Agarwal, Vipin ;

Penzel, Susanne ;

Szekely, Kathrin ;

Cadalbert, Riccardo ;

Testori, Emilie ;

Oss, Andres ;

Past, Jaan ;

Samoson, Ago ;

Ernst, Matthias ;

Boeckmann, Anja ;

Meier, Beat H. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (45) :12253-12256

[14] Dynamic nuclear polarization of spherical nanoparticles [J].

Akbey, Uemit ;

Altin, Burcu ;

Linden, Arne ;

Ozcelik, Serdar ;

Gradzielski, Michael ;

Oschkinat, Hartmut .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (47) :20706-20716

[15] High-Temperature Dynamic Nuclear Polarization Enhanced Magic-Angle-Spinning NMR [J].

Akbey, Uemit ;

Linden, Arne H. ;

Oschkinat, Hartmut .

APPLIED MAGNETIC RESONANCE, 2012, 43 (1-2) :81-90

[16] Dynamic Nuclear Polarization of Deuterated Proteins [J].

Akbey, Uemit ;

Franks, W. Trent ;

Linden, Arne ;

Lange, Sascha ;

Griffin, Robert G. ;

van Rossum, Barth-Jan ;

Oschkinat, Hartmut .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (42) :7803-7806

[17] Optimum levels of exchangeable protons in perdeuterated proteins for proton detection in MAS solid-state NMR spectroscopy [J].

Akbey, Uemit ;

Lange, Sascha ;

Franks, W. Trent ;

Linser, Rasmus ;

Rehbein, Kristina ;

Diehl, Anne ;

van Rossum, Barth-Jan ;

Reif, Bernd ;

Oschkinat, Hartmut .

JOURNAL OF BIOMOLECULAR NMR, 2010, 46 (01) :67-73

[18] Nanosecond Pulses in a THz Gyrotron Oscillator Operating in a Mode-Locked Self-Consistent Q-Switch Regime [J].

Alberti, S. ;

Braunmueller, F. ;

Tran, T. M. ;

Genoud, J. ;

Hogge, J-Ph ;

Tran, M. Q. ;

Ansermet, J-Ph .

PHYSICAL REVIEW LETTERS, 2013, 111 (20)

[19] Experimental study from linear to chaotic regimes on a terahertz-frequency gyrotron oscillator [J].

Alberti, S. ;

Ansermet, J. -Ph. ;

Avramides, K. A. ;

Braunmueller, F. ;

Cuanillon, P. ;

Dubray, J. ;

Fasel, D. ;

Hogge, J. -Ph. ;

Macor, A. ;

de Rijk, E. ;

da Silva, M. ;

Tran, M. Q. ;

Tran, T. M. ;

Vuillemin, Q. .

PHYSICS OF PLASMAS, 2012, 19 (12)

[20]

Alberti S, 2009, 2009 34TH INTERNATIONAL CONFERENCE ON INFRARED, MILLIMETER, AND TERAHERTZ WAVES, VOLS 1 AND 2, P170

← 1 2 3 4 5 6 7 8 9 10 →