FT-IR and Raman spectroscopic studies of gadolinium doped B2O3 • TeO2 glass matrix

被引:26
|
作者
Griguta, L. [1 ]
Ardelean, I. [1 ]
机构
[1] Univ Babes Bolyai, Fac Phys, Cluj Napoca 400084, Romania
来源
MODERN PHYSICS LETTERS B | 2007年 / 21卷 / 26期
关键词
boro-tellurite glasses; gadolinium ions; FT-IR; Raman; VIBRATIONAL-SPECTRA;
D O I
10.1142/S0217984907014152
中图分类号
O59 [应用物理学];
学科分类号
摘要
Glasses from xGd(2)O(3) center dot (100 - x)[B2O3 center dot TeO2] system with 0 <= x <= 10 mol% have been prepared and studied by means of FT-IR absorption and Raman scattering. Being complementary spectroscopic techniques, both types of measurements FT-IR and Raman revealed that the network structure of the studied glasses is based on BO3 and BO4 units placed in different structure groups and also TeO4, TeO3 structural units. No absorption characteristic for Gd2O3 was evidenced but some changes in the structure of B2O3 center dot TeO2 glass matrix are due to its presence.
引用
收藏
页码:1767 / 1774
页数:8
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